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16046-10-9

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16046-10-9 Usage

General Description

2-Acetoxyethyltrimethylsilane, also known by its IUPAC name as trimethyl(2-acetoxyethyl)silane, is a chemical compound with the formula C8H18O2Si. This chemical, categorized under the organosilicon compounds, falls into the class of organic compounds known as trialkylsilyl ethers. These are organic compounds containing an ether with a trialkylsilyl group. 2-Acetoxyethyltrimethylsilane, as a member of silanes, is derived from silane, the simplest silicon hydride. As a chemical, it is commonly used in the research and manufacturing industries due to its versatile nature, as well it is used in various applications like in medical and aerospace industries.

Check Digit Verification of cas no

The CAS Registry Mumber 16046-10-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,0,4 and 6 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 16046-10:
(7*1)+(6*6)+(5*0)+(4*4)+(3*6)+(2*1)+(1*0)=79
79 % 10 = 9
So 16046-10-9 is a valid CAS Registry Number.
InChI:InChI=1/C7H16O2Si/c1-7(8)9-5-6-10(2,3)4/h5-6H2,1-4H3

16046-10-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-trimethylsilylethyl acetate

1.2 Other means of identification

Product number -
Other names ethyl (trimethylsilyl)acetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16046-10-9 SDS

16046-10-9Relevant articles and documents

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Soderquist,J.A.,Thompson,K.L.

, p. 237 - 249 (1978)

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β-Keto esters derived from 2-(trimethylsilyl)ethanol: An orthogonal protective group for β-keto esters

Knobloch, Eva,Brueckner, Reinhard

experimental part, p. 2229 - 2246 (2009/04/08)

β-Keto esters derived from 2-(trimethylsilyl)ethanol undergo cleavage and decarboxylation when treated with 0.75 equivalents of tetrabutylammonium fluoride trihydrate in tetrahydrofuran at 50°C, while β-keto esters derived from methanol, tert-butyl alcohol, allyl alcohol, or benzyl alcohol stay intact. Conversely, methyl-, tert-butyl-, allyl-, or benzyl β-keto esters can be cleaved and decarboxylated without the 2-(trimethylsilyl)ethyl β-keto esters being affected. Similarly, mixed bis(β-keto esters) derived from 2-(trimethylsilyl)ethanol and methanol, tert-butyl alcohol, allyl alcohol, or benzyl alcohol can be defunctionalized chemoselectively under the same reaction conditions. Georg Thieme Verlag Stuttgart.

Effects of Volume and Surface Property in Hydrolysis by Acetylcholinesterase. The Trimethyl Site

Cohen, Saul G.,Elkind, Jerome L.,Chishti, S. Bano,Giner, Jose-L. P.,Reese, Heide,Cohen, Jonathan B.

, p. 1643 - 1647 (2007/10/02)

β-Substituted ethyl acetates, XCH2CH2OCOCH3, have been prepared, and their hydrolysis by acetylcholinesterase has been studied.Log of enzymic reactivity, normalized for intrinsic reactivity in hydrolysis by hydroxide, log(kcat/Km)n, rises linearly with increasing refraction volume, MR (or RD25), for substrates with β-X = H, Cl, Br, CH3CH2, (CH3)2CH, (CH3)2S+, (CH3)3N+, and (CH3)3C.Larger substituents may by accommodated, (CH3)3Si and (CH3CH2)3N+, with no further increase in rate.Substrates with β-substituents CH3S, CH3S(O), (CH3)3N+(OH), and CH3S(O2) are less reactive than consistent with the relation with MR by factors of 5-40, indicating that hydrophobic surface and desolvation of the substrate-enzyme interface may be necessary for maximum reactivity correlated with MR.Values of log (kcat/Km)n for substrates with β-substituents X = CH3S, Cl, Br, CH3CH2, (CH3)2CH, (CH3)3C, and (CH3)3Si rise linearly with increasing hydrophobicity, ?, but reactivity of substrates with X = (CH3)3N+ and (CH3)2S+ are more reactive than consistent with a relation to ? by factors of 300 and 40 and with X = CH3S(O2), CH3S(O), and (CH3)2N+(OH), by factors of 7-100.Reactivity appears related to (i) volume of the β-substituent and its fit in its subsite, which is trimethyl rather than anionic, and (ii) the hydrophobicity of its surface.

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