1609939-60-7

Basic information

• Product Name: 1-methyl-3-phenylbenzo[e][1,2]thiazine 1-oxide
• Synonyms: 1-methyl-3-phenylbenzo[e][1,2]thiazine 1-oxide
• CAS NO: 1609939-60-7
• Molecular Weight: 255.34
• Mol File: 1609939-60-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-methyl-3-phenylbenzo[e][1,2]thiazine 1-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-3-phenylbenzo[e][1,2]thiazine 1-oxide(1609939-60-7)
• EPA Substance Registry System: 1-methyl-3-phenylbenzo[e][1,2]thiazine 1-oxide(1609939-60-7)

Safety Data

• Hazardous Substances Data: 1609939-60-7(Hazardous Substances Data)

Upstream product

• 100-68-5 methyl-phenyl-thioether 
• 98-88-4 benzoyl chloride 
• 20718-17-6 2-(dimethyl(oxo)-λ⁶-sulfaneylidene)-1-phenylethan-1-one 
• 823-46-1 1-deuterio-2-methylsulfanyl-benzene 
• 4381-25-3 S-methyl-S-phenylsulfoximine 
• 19614-16-5 2-bromo-1-(methylsulfanyl)benzene 
• 20187-61-5 mesyloxyacetophenone 
• 7257-94-5 1-phenyl-2-(p-tolylsulfonyloxy)ethanone 

Relevant articles and documents

Water-mediated C-H activation of arenes with secure carbene precursors: The reaction and its application

A water-mediated C-H activation using sulfoxonium ylides is reported, providing a general, green and step-economic approach to construct a C-C bond and varieties of useful N-heterocycle scaffolds. Notably, the "water-mediated" activation, in contrast to that in organic solvents, shows great potential in pharmaceutical, biochemistry and chemical industries.

α-MsO/TsO/Cl ketones as oxidized alkyne equivalents: Redox-neutral rhodium(III)-catalyzed C-H activation for the synthesis of N-heterocycles

α-Halo and pseudohalo ketones are used for the first time as C(sp3)-based electrophiles in transition-metal-catalyzed C-H activation and as oxidized alkyne equivalents in RhIII-catalyzed redox-neutral annulations to generate diverse N-heterocycles. This transformation is efficient and scalable. Due to the mild reaction conditions, a variety of functional groups could be tolerated. Who needs alkynes? α-Halo and pseudohalo ketones (as C(sp3)-based electrophiles) are utilized as oxidized alkyne equivalents in RhIII-catalyzed redox-neutral annulations to efficiently generate diverse N-heterocycles. Owing to the mild reaction conditions, a variety of functional groups are tolerated.