1612226-15-9Relevant articles and documents
Ag(I)-Mediated Oxidative Radical Tri?fluoromethylthiolation of Alkenes
Fang, Ge,Hong, Jianquan,Huang, Shuai,Liu, Yang,Yang, Yupeng,Zhang, Wei,Zheng, Changge
, p. 1324 - 1328 (2019)
A simple, mild, and efficient method for an oxidative radical tri?fluoromethylthiolation of alkenes through AgSCF 3 /K 2 S 2 O 8 system has been developed. This reaction provides a straightforward way to synthesize a variety of useful α-SCF 3 -substituted ketone compounds from a wide range of alkenes in moderate to good yields.
Visible-light-induced oxidative difunctionalization of styrenes: Synthesis of α-trifluoromethylthio-substituted ketones
Yadav, Arvind Kumar,Singh, Krishna Nand
supporting information, p. 1976 - 1979 (2018/03/01)
A novel and practical synthesis of α-trifluoromethylthio-substituted ketones has been accomplished through the visible-light-induced aerobic oxidation of styrenes. The protocol employs the combination of CF3SO2Na and CS2 as a new source of SCF3 radicals in the presence of eosin Y as a photoredox catalyst.
An efficient and practical approach to trifluoromethylthiolation of α-haloketones/α-haloarylmethanes
Jiang, Min,Zhu, Fangxia,Xiang, Haoyue,Xu, Xing,Deng, Lianfu,Yang, Chunhao
, p. 6935 - 6939 (2015/06/25)
An efficient and practical approach to trifluoromethylthiolation of α-haloketones/α-haloarylmethanes was developed. The transformation employs only AgSCF3 and KI in situ generated active nucleophilic trifluoromethylthio species and cleanly occurs in up to quantitative yield at room temperature, thereby providing an unprecedentedly easy entry to various α-SCF3-substituted ketones/arylmethanes.
