1614-06-8

Basic information

• Product Name: 2-(4-NITRO-PHENYL)-1H-IMIDAZOLE
• Synonyms: 2-(4-NITRO-PHENYL)-1H-IMIDAZOLE;2-(4-Nitrophenyl)iMidazole;1H-Imidazole, 2-(4-nitrophenyl)-
• CAS NO: 1614-06-8
• Molecular Formula: C₉H₇N₃O₂
• Molecular Weight: 189.17078
• Mol File: 1614-06-8.mol
• Article Data: 24

Chemical Properties

• Melting Point: 310-312 °C
• Boiling Point: 440.6±28.0 °C(Predicted)
• Appearance: /
• Density: 1.369±0.06 g/cm3(Predicted)
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 11?+-.0.10(Predicted)
• CAS DataBase Reference: 2-(4-NITRO-PHENYL)-1H-IMIDAZOLE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-NITRO-PHENYL)-1H-IMIDAZOLE(1614-06-8)
• EPA Substance Registry System: 2-(4-NITRO-PHENYL)-1H-IMIDAZOLE(1614-06-8)

Safety Data

• Hazardous Substances Data: 1614-06-8(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron, 64, p. 645, 2008 DOI: 10.1016/j.tet.2007.11.009

Upstream product

• 670-96-2 2-Phenylimidazole 
• 98-95-3 nitrobenzene 
• 50846-98-5 2-Diazo-2H-imidazole 
• 555-16-8 4-nitrobenzaldehdye 
• 107-15-3 ethylenediamine 
• 22483-09-6 2,2-dimethoxyethylamine 
• 619-72-7 4-nitrobenzonitrile 
• 288-32-4 1H-imidazole 
• 100-01-6 4-nitro-aniline 
• 122-04-3 4-nitro-benzoyl chloride 
• 61033-70-3 2-(4-nitrophenyl)-4,5-dihydro-1H-imidazoline 
• 7664-93-9 sulfuric acid 
• 861361-81-1 2-(4-nitro-phenyl)-1⁽³⁾H-imidazole-4-carboxylic acid 
• 7732-18-5 water 

Downstream Products

• 13682-33-2 4-(1H-imidazol-2-yl)-aniline 
• 1160826-48-1 C₁₆H₁₀N₄O₅ 
• 1160826-55-0 C₁₆H₁₀BrN₃O₃ 
• 1220701-15-4 C₁₄H₁₁N₅O₂S 
• 1253697-42-5 2-(4-nitrophenyl)-1-(phenylsulfonyl)-1H-imidazole 
• 1400866-35-4 C₁₇H₁₄N₄O₃ 
• 1400866-39-8 C₂₀H₂₀N₄O₃ 
• 245547-15-3 4-(1-methyl-1H-imidazol-2-yl)aniline 

Relevant articles and documents

Direct Oxidative Conversion of Benzoyl Chlorides to 2-Imidazoles Using Heteropolyacids

The reaction of benzoyl chlorides with ethylenediamine in the presence of catalytic amounts of Keggin-type heteropolyacids led to oxidative conversion of benzoyl chlorides to the corresponding 2-imidazoles in good yields.

Highly efficient protocol for the aromatic compounds nitration catalyzed by magnetically recyclable core/shell nanocomposite

An efficient protocol for the nitration of aromatic compounds in the presence of a catalytic amount of sulfuric acid-functionalized silica-based magnetic core/shell nanocomposite was reported. The designed products were obtained in high yields in relatively short reaction times at room temperature under solvent-free conditions. The nanocatalyst was simply recovered from the reaction mixture by using an external magnet and efficiently reused for several times. The characterization of particle size, morphology and elemental analysis of the nanocatalyst were provided by scanning electron microscopy, transmission electron microscopy and energy-dispersive X-ray spectroscopy analyses, respectively.

Fe3O4/SiO2/(CH2)3N+Me3Br3- core-shell nanoparticles: A novel catalyst for the solvent-free synthesis of five- and six-membered heterocycles

Functionalized magnetic core-shell nanoparticles [Fe3O4/SiO2/(CH2)3N+Me3Br3-] are prepared by co-precipitation method, characterized by transmission electron microscopy, FT-IR, X-ray diffraction, and vibrating sample magnetometer. The catalytic activity of these nanoparticles was tested in the syntheses of imidazole, benzothiazole, and perimidine derivatives, under solvent-free conditions. The catalyst was readily recycled by the use of an external magnetic field and could be reused five times without significant loss of activity or mass.