16155-34-3

Basic information

• Product Name: n-butyl(4-Chlorophenyl) sulfane
• Synonyms: n-butyl(4-Chlorophenyl) sulfane
• CAS NO: 16155-34-3
• Molecular Formula: C₁₀H₁₃ClS
• Molecular Weight: 200.73
• Mol File: 16155-34-3.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 127 °C(Press: 7 Torr)
• Appearance: /
• Density: 1.10±0.1 g/cm3(Predicted)
• CAS DataBase Reference: n-butyl(4-Chlorophenyl) sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: n-butyl(4-Chlorophenyl) sulfane(16155-34-3)
• EPA Substance Registry System: n-butyl(4-Chlorophenyl) sulfane(16155-34-3)

Safety Data

• Hazardous Substances Data: 16155-34-3(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 1146-44-7 4,4'-dichlorophenyl thiosulfonate 
• 542-69-8 1-iodo-butane 
• 52943-93-8 (E)-2-<(4-Chlorphenylthio)methylen>-6,6-dimethylcyclohexanon 
• 109-69-3 n-Butyl chloride 
• 106-54-7 p-Chlorothiophenol 
• 778-28-9 butyl para-toluenesulfonate 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 637-87-6 1-Chloro-4-iodobenzene 
• 629-45-8 dibutyl disulfide 
• 86409-62-3 tricarbonyl(1,4-dichlorobenzene)chromium⁽⁰⁾ 
• 109-79-5 n-butanethiol 
• 1207372-98-2 butyl 2-[2-(4-methoxyphenyl)ethynyl]benzoate 
• 29540-84-9 4-chlorophenyl trifluoromethanesulfonate 

Downstream Products

• 6344-43-0 4-chlorophenyl-n-butylsulfone 
• 1205-71-6 N-(4-chlorophenyl)aniline 

Relevant articles and documents

Microwave assisted, highly efficient solid state N- and S-alkylation

Secondary amines and thiophenols were alkylated with alkyl and benzyl halides rapidly on alumina supported potassium carbonate under solvent-free conditions using microwaves. Equimolar amounts of the secondary amine/thiophenol and alkyl halide were used. The procedure neither required any strong base nor a PTC Aniline was also monobenzylated with benzylchloride. Separation of the products from the reactants was very simple by using a nonpolar solvent for desorption.

Ullmann-type: N-arylation of anilines with alkyl(aryl)sulfonium salts

A palladium/copper-cocatalyzed Ullmann-type N-arylation of anilines using alkyl(aryl)sulfonium triflates as arylation reagents has been accomplished. The reaction enabled Caryl-S bond cleavage over Calkyl-S bond breakage of alkyl(aryl)sulfoniums by Pd(P(tBu)3)2/CuI and gave the corresponding N-arylated products in good to high yields. It was also significant that the reactions of aniline with asymmetric butyl(mesityl)(aryl)sulfonium triflates showed excellent selectivity, in which the aryl groups other than the bulky and electron-rich mesityl moieties were transformed.

Cu-Catalyzed Coupling of Aryl Iodides with Thiols Using Carbonyl-Phosphine Oxide Ligands

A series of carbonyl-phosphine oxide ligands were synthesized from 2-bromophenylaldehyde and used in Cu-catalyzed C-S coupling reactions. Aryl iodide and aryl bromide reacted with thiols efficiently upon catalysis under mild reaction conditions and a yiel