16446-29-0

Basic information

• Product Name: 5(4H)-Thiazolone, 2-phenyl-
• CAS NO: 16446-29-0
• Molecular Formula: C9H7NOS
• Molecular Weight: 177.227
• Mol File: 16446-29-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 5(4H)-Thiazolone, 2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 5(4H)-Thiazolone, 2-phenyl-(16446-29-0)
• EPA Substance Registry System: 5(4H)-Thiazolone, 2-phenyl-(16446-29-0)

Safety Data

• Hazardous Substances Data: 16446-29-0(Hazardous Substances Data)

Upstream product

• 7471-86-5 methyl benzimidate 
• 87386-07-0 N-(thiobenzoyl)glycine ethyl ester 
• 5873-86-9 methyl thiobenzoate 
• 2584-64-7 N-(thiobenzoyl)glycine 

Downstream Products

• 128870-92-8 4-((Z)-4-methyl-benzylidene)-2-phenyl-4H-thiazol-5-one 
• 82865-29-0 (Z)-4-benzylidene-2-phenylthiazol-5(4H)-one 
• 151103-91-2 acetic acid-(2-phenyl-thiazol-5-yl ester) 
• 858202-90-1 N-thiobenzoyl-glycine-(N'-phenyl-hydrazide) 
• 35352-73-9 4-isopropylidene-2-phenyl-4H-thiazol-5-one 
• 35317-71-6 diphenylacetic acid 4-(2-acetoxy-1-methyl-vinyl)-2-phenyl-thiazol-5-yl ester 
• 16446-03-0 4-[2-(5'-chloro-8'-methoxy-3',4'-dihydro-2'H-spiro[[1,3]dioxolane-2,1'-naphthalen]-3'-yl)-ethylidene]-2-phenyl-4H-thiazol-5-one 
• 35317-65-8 4-((Z)-2-acetoxy-1-methyl-ethylidene)-2-phenyl-4H-thiazol-5-one 
• 35317-64-7 4-(2-acetoxy-1-acetoxymethyl-ethylidene)-2-phenyl-4H-thiazol-5-one 
• 70489-49-5 4-[2-(5,7-dimethoxy-4-oxo-1,2,3,4-tetrahydro-naphthalen-2-yl)-ethylidene]-2-phenyl-4H-thiazol-5-one 
• 35317-72-7 5-acetoxy-4-(2-acetoxy-1-methyl-vinyl)-2-phenyl-thiazole 
• 16446-30-3 4-benzylidene-2-phenyl-4H-thiazol-5-one 
• 69673-63-8 4-(7-hydroxy-2,2,10b-trimethyl-6-oxo-(4ar,10bc)-4a,5,6,10b-tetrahydro-4H-naphtho[1,2-d][1,3]dioxin-4c-ylmethylene)-2-phenyl-4H-thiazol-5-one 
• 24053-33-6 5-acetylsulfanyl-2-phenyl-thiazole 

Relevant articles and documents

Improved erlenmeyer synthesis with 5-thiazolone and catalytic Mn(II) acetate. Crystal structure confirmation of the reaction stereochemistry

2-Phenylthiazolin-5-one (5, a thioazlactone) condenses with various aldehydes in the presence of the mild base Mn(II) acetate as catalyst in CH 2Cl2 solution. This leads to the corresponding Erlenmeyer reaction products (6) in excell

REACTION OF 5(4H)-THIAZOLONES WITH DIAZOMETHANE

The reaction of diazomethane with several (Z)-2-substituted-4-benzylidene-5(4H)thiazolones (1) (2-substitution: SCH2Ph, OCH2Ph, SCH3, CH3, Ph), under two different conditions, has been studied.In benzene at 45 deg C (Z) and (E)-2-substituted-1-phenyl-7-ox