16463-18-6

Upstream product

• 7205-66-5 1-(1,1-dimethylethyl)sulfanyl-4-nitrobenzene 
• 350-46-9 4-Fluoronitrobenzene 
• 75-66-1 2-methylpropan-2-thiol 
• 100-00-5 4-chlorobenzonitrile 
• 1849-36-1 para-nitrobenzenethiol 
• 163319-03-7 ((C₆H₅)2PCH₂CH₂P(C₆H₅)2)Pd(SC(CH₃)3)(C₆H₄NH₂) 
• 24762-44-5 triphenylphosphine-d15 
• 7439-89-6 iron 

Downstream Products

• 916503-43-0 4,9-dichloro-2,7-bis{4-[(1,1-dimethylethyl)sulfanyl]phenyl}benzo[lmn][3,8]phenanthroline-1,3,6,8-(2H,7H)-tetrone 
• 65688-19-9 1-(tert-butylsulfanyl)-4-iodobenzene 
• 1236410-19-7 ethyl 3-(4-(tert-butylthio)phenylamino)propanoate 
• 916503-44-1 4,9-bis{[3,5-bis(1,1-dimethylethyl)phenyl]amino}-2,7-bis{4-[(1,1-dimethylethyl)sulfanyl]phenyl}benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetrone 
• 916503-45-2 4,9-bis{[3,5-bis(1,1-dimethylethyl)phenyl]oxy}-2,7-bis{4-[(1,1-dimethylethyl)sulfanyl]phenyl}benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetrone 
• 916503-50-9 4,9-bis({[4-(1,1-dimethylethyl)phenyl]methyl}selanyl)-2,7-bis{4-[(1,1-dimethylethyl)sulfanyl]phenyl}benzo[3.8]phenanthroline-1,3,6,8(2H,7H)-tetrone 
• 916503-47-4 4,9-bis({[4-(1,1-dimethylethyl)phenyl]methyl}amino)-2,7-bis{4-[(1,1-dimethylethyl)sulfanyl]phenyl}benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetrone 
• 916503-56-5 4-({[4-(1,1-dimethylethyl)phenyl]methyl}amino)-9-({[4-(1,1-dimethylethyl)phenyl]methyl}sulfanyl)-2,7-bis{4-[(1,1-dimethylethyl)sulfanyl]phenyl}benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetrone 
• 916503-49-6 4,9-bis({[4-(1,1-dimethylethyl)phenyl]methyl}sulfanyl)-2,7-bis{4-[(1,1-dimethylethyl)sulfanyl]phenyl}benzo[3.8]phenanthroline-1,3,6,8(2H,7H)-tetrone 
• 916503-48-5 4,9-bis({[4-(1,1-dimethylethyl)phenyl]methyl}oxy)-2,7-bis{4-[(1,1-dimethylethyl)sulfanyl]phenyl}benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetrone 
• 916503-46-3 4,9-bis{[4-(1,1-dimethylethyl)phenyl]sulfanyl}-2,7-bis{4-[(1,1-dimethylethyl)sulfanyl]phenyl}benzo[lmn][3,8]phenanthroline-1,3,6,8(2H,7H)-tetrone 

Relevant academic research and scientific papers

Oligonucleotide and use thereof

Provided is an oligonucleotide containing an azobenzene derivative, represented by Formula (1) or (2) below: (in the formulae, A1 and A2 each independently represent a hydrogen atom, nucleotide or oligonucleotide, B1 and B

OXIME DERIVATIVE, METHOD OF PRODUCING THE SAME AND INSECTICIDE COMPRISING THE SAME AS ACTIVE INGREDIENT

PROBLEM TO BE SOLVED: To provide a compound having excellent insecticidal effect and useful as an active ingredient of an insecticide. SOLUTION: This invention provides an oxime derivative represented by general formula (1) (where Ra, X and n represent definitions described in the specifications) and an insecticide that comprises the same as an active ingredient. COPYRIGHT: (C)2015,JPOandINPIT

4-AMINO-7,8-DIHYDROPYRIDO[4,3-d]PYRIMIDIN-5(6H)-ONE DERIVATIVES

The invention provides compounds of the general Formula (I) where R1, R2, and A are defined herein, as well as the preparation, compositions and uses thereof.

Synthesis, structure, and optical properties of terminally sulfur-functionalized core-substituted naphthalene-bisimide dyes

The synthesis, characterization, and optical properties of a series of new 2,6-disubstituted naphthalene-bisimide dyes as molecular rods comprising terminal AcS groups is reported. The first series of dyes (1-3), comprising phenylhetero (Ph-X) core substituents, cover a broad range of the VIS spectrum, ranging from yellow (2) over red (3) to blue (1). The second series of dyes contains benzylhetero (Bn-X) core substituents (4-7). For the same heteroatom connecting the substituent to the naphthalene core, both series were found to display comparable colors. For the second series, the colors were blue (4), red (5), and violet (6, 7). The Ph-X-substituted dyes 1-3 are nonfluorescent, in contrast to the Bn-X-substituted compounds 4-7. This rich variety of optical features that can be adjusted by rather small alterations of the core substituents makes these structurally very comparable molecular rods ideal candidates for optically triggered molecular-transport investigations. Also, thanks to the terminal AcS groups, these compounds can be placed between nobel-metal electrodes for optically triggered transport experiments.

Carbon-sulfur bond-forming reductive elimination involving sp-, sp2-, and sp3-hybridized carbon. Mechanism, steric effects, and electronic effects on sulfide formation

Palladium thiolato complexes [(L)Pd(R)(SR')], within which L is a chelating ligand such as DPPE, DPPP, DPPBz, DPPF, or TRANSPHOS, R is a methyl, alkenyl, aryl, or alkynyl ligand, and R' is an aryl or alkyl group, were synthesized by substitution or proton-transfer reactions. All of these thiolato complexes were found to undergo carbon-sulfur bond-forming inductive elimination in high yields to form dialkyl sulfides, diaryl sulfides, alkyl aryl sulfides, alkyl alkenyl sulfides, and alkyl alkynyl sulfides. Reductive eliminations forming alkenyl alkyl sulfides and aryl alkyl sulfides were the fastest. Eliminations of alkynyl alkyl sulfides were slower, and elimination of dialkyl sulfide was the slowest. Thus the relative rates for sulfide elimination as a function of the hybridization of the palladium-bound carbon follow the trend sp2 > sp >> sp3. Rates of reductive elimination were faster for cis-chelating phosphine ligands with larger bite angles. Kinetic studies, along with results from radical trapping reactions, analysis of solvent effects; and analysis of complexes with chelating phosphines of varying rigidity, were conducted with [Pd(L)(S-tert-butyl)(Ar)] and [Pd(L)(S- tert-butyl)(Me)]. Carbon-sulfur bond-forming reductive eliminations involving both saturated and unsaturated hydrocarbyl groups proceed by an intramolecular, concerted mechanism. Systematic changes in the electronic properties of the thiolate and aryl groups showed that reductive elimination is the fastest for electron deficient aryl groups and electron rich arenethiolates, suggesting that the reaction follows a mechanism in which the thiolate acts as a nucleophile and the aryl group an electrophile. Studies with thiolate ligands and hydrocarbyl ligands of varying steric demands favor a migration mechanism involving coordination of the hydrocarbyl ligand in the transition state.

Substituted-4-alkylthioalkane-sulfonanilides and operatives

Alkane- and monohaloalkane-sulfonanilides substituted in the para position by alkylthio, alkylsulfinyl and alkylsulfonyl groups and additionally substituted by halogen and optionally by trifluoromethyl and agriculturally acceptable salts thereof are useful herbicides.

3-Pyridylmethyl aryl urea rodenticides compositions

Rodenticidal compositions containing as the active ingredient novel 1-(3-pyridylmethyl)-3-(4'-substituted-phenyl or -naphthyl)ureas and their acid addition salts. The 4'-substituent may be nitro, cyano, trifluoromethyl, butyryl, thiocyano, alkylthio, phenylsulfonyl or diethylsulfonamide.

3-Pyridylmethyl aryl urea rodenticides

Novel 1-(3-pyridylmethyl)-3-(4'-substituted-phenyl or -naphthyl)-ureas and their acid addition salts. The 4'-substituent may be --NO2, --CN, --CF3, --C(O)R1, --SCN, SR2, --SO2 C6 H5 or --SO2 NR3 R4. These compounds are biologically active, and many are active rodenticides.