165874-36-2

Basic information

• Product Name: Cyclohexanone, 5-methyl-2-(1-methylethyl)-, oxime, (2R,5S)- (9CI)
• Synonyms: Cyclohexanone, 5-methyl-2-(1-methylethyl)-, oxime, (2R,5S)- (9CI)
• CAS NO: 165874-36-2
• Molecular Formula: C10H19NO
• Molecular Weight: 169.26396
• Product Categories: ISOPROPYL
• Mol File: 165874-36-2.mol
• Article Data: 18

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclohexanone, 5-methyl-2-(1-methylethyl)-, oxime, (2R,5S)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 5-methyl-2-(1-methylethyl)-, oxime, (2R,5S)- (9CI)(165874-36-2)
• EPA Substance Registry System: Cyclohexanone, 5-methyl-2-(1-methylethyl)-, oxime, (2R,5S)- (9CI)(165874-36-2)

Safety Data

• Hazardous Substances Data: 165874-36-2(Hazardous Substances Data)

Upstream product

• 10458-14-7 Menthone 
• 72020-06-5 2-(2-isopropyl-5-methylcyclohexyloxy)tetrahydro-2H-pyran 
• 62338-23-2 (2-isopropyl-5-methylcyclohexyloxy)trimethylsilane 
• 10458-14-7 (2R,5S)-menthone 
• 17627-49-5 (–)-menthone 
• 3391-87-5 l-menthone 
• 491-07-6 (+/-)-menthone 
• 2216-51-5 (-)-menthol 
• 546-88-3 acetylhydroxamic acid 
• 94827-79-9 3-Chlor-3-nitroso-1-methyl-4-isopropyl-cyclohexan 
• 75-24-1 trimethylaluminum 

Downstream Products

• 93810-98-1 N-neomenthyl-benzamide 
• 51743-63-6 (+)-neomenthylamine 
• 1667-73-8 p-menthan-3-one-(O-benzoyl oxime ) 
• 13559-68-7 3-Acetoxy-3(a)-nitrosomenthan 
• 33059-60-8 3-Nitro-3-acetoxy-menthan 
• 33045-08-8 3-Nitroso-3-benzoyloxy-menthan 
• 33044-98-3 (-)-c-3-Chlor-t-3-nitroso-r-1-p-menthan 
• 33045-06-6 3-Brom-3-nitroso-menthan 
• 13559-68-7 1-Acetoxy-1-nitroso-2-isopropyl-5-methyl-cyclohexan 
• 120625-76-5 C₁₇H₂₂N₄O₆ 
• 85081-39-6 (2S,trans)-perhydro-2-isopropyl-5-methylazepine 
• 114048-88-3 (3S,6R)-3-isopropyl-6-methylhexahydroazepin-2-one 
• 50517-54-9 (-)-(4R,trans)-4,5,6,7-tetrahydro-7-isopropyl-4-methylazepin-2(3H)-one 
• 160399-90-6 isomenthylamine 

Relevant articles and documents

Chiral palladium complexes with monoterpenoids oximes

Oximes of cis-caran-4-one, 3α- and 3β-hydroxycaran-4-ones, cis-verbanone, menthone, and 2β-hydroxybornan-3-one have been synthesized. The obtained oximes react with lithium tetrachloropalladate to give new chiral palladium complexes containing mono-or bid

Atypical and Asymmetric 1,3-P,N Ligands: Synthesis, Coordination and Catalytic Performance of Cycloiminophosphanes

Novel seven-membered cyclic imine-based 1,3-P,N ligands were obtained by capturing a Beckmann nitrilium ion intermediate generated in situ from cyclohexanone with benzotriazole, and then displacing it by a secondary phosphane under triflic acid promotion. These “cycloiminophosphanes” possess flexible non-isomerizable tetrahydroazepine rings with a high basicity; this sets them apart from previously reported iminophophanes. The donor strength of the ligands was investigated by using their P-κ1- and P,N-κ2-tungsten(0) carbonyl complexes, by determining the IR frequency of the trans-CO ligands. Complexes with [RhCp*Cl2]2 demonstrated the hemilability of the ligands, giving a dynamic equilibrium of κ1 and κ2 species; treatment with AgOTf gives full conversion to the κ2 complex. The potential for catalysis was shown in the RuII-catalyzed, solvent-free hydration of benzonitrile and the RuII- and IrI-catalyzed transfer hydrogenation of cyclohexanone in isopropanol. Finally, to enable access to asymmetric catalysts, chiral cycloiminophosphanes were prepared from l-menthone, as well as their P,N-κ2-RhIII and a P-κ1-RuII complexes.

MgFe2O4@SiO2-PrNH2/Pd/bimenthonoxime core-shell magnetic nanoparticles as a recyclable green catalyst for heterogeneous Suzuki cross-coupling in aqueous ethanol

Magnetically recoverable MgFe2O4@SiO2-PrNH2/Pd/bimenthonoxime nanoparticles were prepared and characterized by SEM, EDX, TEM, XRD, XPS, ICP, VSM and FT-IR. The nanocatalyst was used for Suzuki cross-coupling in