16626-54-3Relevant academic research and scientific papers
Tandem rhodium-catalyzed hydroformylation-hydrogenation of alkenes by employing a cooperative ligand system
Fuchs, Daniela,Rousseau, Geraldine,Diab, Lisa,Gellrich, Urs,Breit, Bernhard
supporting information; experimental part, p. 2178 - 2182 (2012/04/10)
Dual action: A multifunctional rhodium catalyst system enables the simultaneous catalysis of two distinct transformations, hydroformylation of an alkene and reduction of an aldehyde, in a highly selective manner. This one-pot/two-step process is controlled by the cooperative action of two different supramolecular ligand systems and transforms terminal alkenes into C1-chain-elongated linear alcohols. Copyright
Reductive Carbonylation of Alkenes using Zwitterionic Rhodium Complexes as Catalysts
Zhou, Jian-Qiang,Alper, Howard
, p. 233 - 234 (2007/10/02)
Alkenes react with carbon monoxide, sodium borohydride, propan-2-ol and a catalytic amount of Rh(cod)(η6-PhBPh3) (cod = cyclooctadiene) to give alcohols in fine yields; high regioselectivity for the branched or linear alcohol is usually observed, depending on the organic substrate.
