16660-57-4Relevant articles and documents
Induced alkene reactions with sulfur dichloride. System sulfur dichloride - Dimethyl sulfide as a reagent for polysulfonation and conjugate chlorination of alkenes
Bodrikov,Sazhin,Shebelova,Subbotin,Rybalova,Gatilov,Barkhash
, p. 1105 - 1112 (2007/10/03)
In reaction of unsaturated compounds with sulfur dichloride in the presence of dimethyl sulfide radically new induced directions are realized: the reagent is involved as dimer or trimer (formation of di- and trisulfides). Alongside this process a conjugate chlorination occurred with participation of external nucleophiles, dimethyl sulfide and acetonitrile, furnishing sulfonium chlorides and N-substituted acetamides respectively. The relative importance of these alternative reactions depends on solvent, alkene structure, and order of reagents addition.