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16766-63-5

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16766-63-5 Usage

General Description

3-phenyl-tetrahydrofuran is a chemical compound that consists of a tetrahydrofuran ring with a phenyl group attached at the 3-position. It is an organic compound and part of the family of furans, which are cyclic organic compounds. 3-phenyl-tetrahydrofuran is used in organic synthesis as a building block or intermediate for the production of various pharmaceuticals, agrochemicals, and other organic compounds. It has also been studied for its potential use in materials science and as a solvent in chemical reactions. The compound is known for its stability and relative safety when handled and has attracted research interest for its potential applications in various fields.

Check Digit Verification of cas no

The CAS Registry Mumber 16766-63-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,7,6 and 6 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 16766-63:
(7*1)+(6*6)+(5*7)+(4*6)+(3*6)+(2*6)+(1*3)=135
135 % 10 = 5
So 16766-63-5 is a valid CAS Registry Number.

16766-63-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-Phenyl-tetrahydrofuran

1.2 Other means of identification

Product number -
Other names 3-phenyloxolane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16766-63-5 SDS

16766-63-5Relevant articles and documents

Electrochemically Enabled, Nickel-Catalyzed Dehydroxylative Cross-Coupling of Alcohols with Aryl Halides

Li, Zijian,Sun, Wenxuan,Wang, Xianxu,Li, Luyang,Zhang, Yong,Li, Chao

supporting information, p. 3536 - 3543 (2021/03/08)

As alcohols are ubiquitous throughout chemical science, this functional group represents a highly attractive starting material for forging new C-C bonds. Here, we demonstrate that the combination of anodic preparation of the alkoxy triphenylphosphonium ion and nickel-catalyzed cathodic reductive cross-coupling provides an efficient method to construct C(sp2)-C(sp3) bonds, in which free alcohols and aryl bromides - both readily available chemicals - can be directly used as coupling partners. This nickel-catalyzed paired electrolysis reaction features a broad substrate scope bearing a wide gamut of functionalities, which was illustrated by the late-stage arylation of several structurally complex natural products and pharmaceuticals.

Iron-Catalyzed Ring-Closing C?O/C?O Metathesis of Aliphatic Ethers

Biberger, Tobias,Makai, Szabolcs,Lian, Zhong,Morandi, Bill

supporting information, p. 6940 - 6944 (2018/05/14)

Among all metathesis reactions known to date in organic chemistry, the metathesis of multiple bonds such as alkenes and alkynes has evolved into one of the most powerful methods to construct molecular complexity. In contrast, metathesis reactions involving single bonds are scarce and far less developed, particularly in the context of synthetically valuable ring-closing reactions. Herein, we report an iron-catalyzed ring-closing metathesis of aliphatic ethers for the synthesis of substituted tetrahydropyrans and tetrahydrofurans, as well as morpholines and polycyclic ethers. This transformation is enabled by a simple iron catalyst and likely proceeds via cyclic oxonium intermediates.

Asymmetric hydrogenation of furans and benzofurans with iridium-pyridine-phosphinite catalysts

Pauli, Larissa,Tannert, Re,Scheil, Robin,Pfaltz, Andreas

, p. 1482 - 1487 (2015/01/30)

Enantioselective hydrogenation of furans and benzofurans remains a challenging task. We report the hydrogenation of 2- and 3-substituted furans by using iridium catalysts that bear bicyclic pyridine-phosphinite ligands. Excellent enantioselectivities and high conversions were obtained for monosubstituted furans with a 3-alkyl or 3-aryl group. Furans substituted at the 2-position and 2,4-disubstituted furans proved to be more difficult substrates. The best results (80-97% conversion, 65-82% enantiomeric excess) were obtained with monosubstituted 2-alkylfurans and 2-[4-(trifluoromethyl)phenyl]furan. Benzofurans with an alkyl substituent at the 2- or 3-position also gave high conversions and enantioselectivity, whereas 2-aryl derivatives showed essentially no reactivity. The asymmetric hydrogenation of a 3-methylbenzofuran derivative was used as a key step in the formal total synthesis of the cytotoxic naphthoquinone natural product (-)-thespesone.

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