17082-14-3

Upstream product

• 70-11-1 α-bromoacetophenone 
• 546-88-3 acetylhydroxamic acid 
• 2142-69-0 2-bromophenyl methyl ketone 
• 98-86-2 acetophenone 

Downstream Products

• 101734-36-5 3-benzoyl-1-phenyl-pentane-1,4-dione-1-(Z)-oxime 
• 79750-76-8 2,4-diphenyl-1-p-tolyl-2,5-dihydro-1H-imidazole 3-oxide 
• 87618-62-0 2-methoxy-2-methyl-5-phenyl-3,4-dihydro-2H-pyrrole 1-oxide 
• 152511-66-5 3-(4-methoxy-phenyl)-2,5-diphenyl-3,4-dihydro-2H-imidazole-1-oxide 
• 152511-67-6 1-(4-Bromo-phenyl)-2,4-diphenyl-2,5-dihydro-1H-imidazole 3-oxide 
• 152511-63-2 2-Benzo[1,3]dioxol-5-yl-1,4-diphenyl-2,5-dihydro-1H-imidazole 3-oxide 
• 152511-62-1 2-(2,3-Dimethoxy-phenyl)-1,4-diphenyl-2,5-dihydro-1H-imidazole 3-oxide 
• 16451-83-5 syn-α-(Dimethylamino)acetophenone oxime 
• 92579-22-1 anti-α-Methylanilino-acetophenon-oxim 
• 95433-07-1 anti-α--acetophenon-oxim-<4-methoxy-benzoat> 
• 94872-46-5 anti-α--acetophenon-oxim-<2.4-dinitro-phenylaether> 
• 100372-82-5 3-(β-hydroxyimino-phenethyl)-pentane-2,4-dione 
• 34277-26-4 1,4-bis-(2-hydroxyimino-2-phenyl-ethyl)-1-[2-(2-methoxy-phenothiazin-10-yl)-1-methyl-ethyl]-4-[2-(3,4,5-trimethoxy-benzoyloxy)-ethyl]-piperazinediium; dibromide 
• 29441-71-2 7a-morpholin-4-yl-3-phenyl-4,4a,5,6,7,7a-hexahydro-cyclopenta[e][1,2]oxazine 

Relevant academic research and scientific papers

Insulinomimetic vanadyl-hydroxythiazolethione complexes with VO(S 2O2) coordination mode: The correlation between the activity and Hammett's substituent constant

Four kinds of vanadyl-hydroxythiazolethione complexes with VO(S 2O2) coordination mode were newly synthesized, and demonstrated for the first time that the insulinomimetic activity apparently correlates to the Hammett's substituent c

α-Nitrosostyrenes as Three-Atom Units for the (3+1) Cyclization Reaction: Facile Access to 2,3-Dihydrodiazete N-Oxides and Their Diversified Synthetic Conversions

An unprecedented (3+1) cyclization of α-nitrosostyrenes, generated in situ from α-bromooximes, and N-tosyloxycarbamates was developed, which enables the synthesis of a range of structurally unique and hitherto unexplored 2,3-dihydrodiazete N-oxides in mod

Copper-Catalyzed Annulation of Oxime Acetates with α-Amino Acid Ester Derivatives: Synthesis of 3-Sulfonamido/Imino 4-Pyrrolin-2-ones

A copper-catalyzed annulation of oxime acetates and α-amino acid ester derivatives for the easy preparation of 4-pyrrolin-2-ones bearing a 3-amino group has been developed. This process features the oxidation of amines with oxime esters as the internal oxidant to produce the active 1,3-dinucleophilic and 1,2-dielectrophilic species concurrently. The subsequent nucleophilic cyclization realizes the efficient construction of 4-pyrrolin-2-one derivatives.

An efficient synthesis of 2-isoxazolines from α-haloketone oximes and dimethyl sulfonium salts

2-Isoxazolines were synthesized efficiently from a formal [4+1] cycloaddition of nitrosoalkenes and sulfur ylides, which were generated in situ from α-haloketone oximes and dimethyl sulfonium salts. This approach provides a new method to synthesize a rang

A DEVELOPING AGENT PRECURSOR FOR LASER MARKABLE COMPOSITIONS

The invention relates to novel laser markable compositions comprising developing agent precursors according to formula (I).

Synthesis and Beckmann rearrangement of novel (Z)-2-organylselanyl ketoximes: promising agents against grapevine anthracnose infection

We present here the synthesis of novel (Z)-2-organylselanyl ketoximes by nucleophilic substitution reaction of E/Z mixtures of 2-bromo ketoximes with nucleophilic species of selenium, which were generated in situ by simple cleavage of diorganyl diselenides with NaBH4using ethanol/THF as solvent. The new 2-organylselanyl ketoximes were synthesized in moderate to good yields and with selectivity for the (Z)-configuration. The synthesized (Z)-2-arylselanylacetophenone oximes were submitted to the Beckmann rearrangement, furnishing the corresponding N-aryl-2-(selanyl)acetamides. (Z)-1-Phenyl-2-(phenylselanyl) ketoxime has antifungal activity against Sphaceloma ampelinum and a good level of antioxidant activity in vitro in DPPH, ABTS, FRAP and lipid peroxidation assays.

Nitrimines as reagents for metal-free formal C(sp2)-C(sp2) cross-coupling reactions

Nitrimines are employed as powerful reagents for metal-free formal C(sp2)-C(sp2) cross-coupling reactions. The new chemical process is tolerant of a wide array of nitrimine and heterocyclic coupling partners giving rise to the corresponding di- or trisubstituted alkenes, typically in high yield and with high stereoselectivity. This method is ideal for the metal-free construction of heterocycle-containing drug targets, such as phenprocoumon.

Replacement of the Methylene of Dihydrochalcones with Oxygen: Synthesis and Biological Evaluation of 2-Phenoxyacetophenones

With the aim of finding new bioactive compounds, a series of phenoxyacetophenone derivatives 2 were designed and synthesized as oxygen analogs of dihydrochalcones. Also, phenoxyacetophenones were converted to (Z)-oxime derivatives 3 and their geometry wer

Europium(III) triflate-catalyzed Trofimov synthesis of polyfunctionalized pyrroles

The synthesis of polyfunctionalized pyrroles by reaction of a ketoxime with dimethyl acetylenedicarboxylate using europium(III) triflate as the catalyst is described. Copyright

Cycloaddition of nitrones with arynes generated from benzobisoxadisilole or 2,3-naphthoxadisilole

1,3-Dipolar cycloaddition of nitrones with arynes generated in situ from benzobisoxadisilole or 2,3-naphthoxadisilole afforded the oxadisilole fused benzo[d]isoxazoline or the naphtho[2,3-d]isoxazoline derivatives at room temperature in good yields.