171504-25-9

Upstream product

• 216978-35-7 Acetic acid 5-(tert-butyl-dimethyl-silanyloxymethyl)-2,6,6-trimethyl-cyclohex-1-enylmethyl ester 
• 216978-34-6 1-Acetoxymethyl-5-hydroxymethyl-2,6,6-trimethylcyclohex-1-ene 
• 144066-82-0 Acetic acid 2-isopropenyl-3-methyl-but-2-enyl ester 
• 144067-40-3 Acetic acid 5-formyl-2,6,6-trimethyl-cyclohex-1-enylmethyl ester 
• 171504-24-8 [5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,6,6-trimethyl-cyclohex-1-enyl]-methanol 
• 882-33-7 diphenyldisulfane 

Downstream Products

• 318949-66-5 5-Hydroxymethyl-1-[2-(1-methylcyclohexa-2,5-dien-1-yl)-2-hydroxy-1-phenylsulfonylethyl]-2,6,6-trimethylcyclohex-1-ene 
• 318949-67-6 3-[1-benzenesulfonyl-2-hydroxy-2-(1-methyl-cyclohexa-2,5-dienyl)-ethyl]-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde 
• 318949-75-6 {2,2,4-Trimethyl-3-[(E)-2-(1-methyl-cyclohexa-2,5-dienyl)-vinyl]-cyclohex-3-enyl}-methanol 
• 318949-70-1 (Z)-5-tert-Butyldimethylsilyloxymethyl-1-[2-(1-methylcyclohexa-2,5-dien-1-yl)ethenyl]-2,6,6-trimethylcyclohex-1-ene 
• 173438-12-5 2,2,4-Trimethyl-3-[(E)-2-(1-methyl-cyclohexa-2,5-dienyl)-vinyl]-cyclohex-3-enecarbaldehyde 
• 173438-11-4 2,2,4-Trimethyl-3-[(Z)-2-(1-methyl-cyclohexa-2,5-dienyl)-vinyl]-cyclohex-3-enecarbaldehyde 
• 320381-91-7 2,2,4-trimethyl-3-<2-(1-methyl-4-trimethylsilylcyclohexa-2,5-dienyl)vinyl>cyclohex-3-ene-1-carbaldehyde 
• 318949-71-2 (Z)-5-Hydroxymethyl-1-[2-(1-methylcyclohexa-2,5-dien-1-yl)ethenyl]-2,6,6-trimethylcyclohex-1-ene 
• 171504-34-0 5-tert-butyldimethylsiloxymethyl-1-<2-hydroxy-2-(1-methyl-2,5-cyclohexadien-1-yl)-1-phenylsulfonylethyl>-2,6,6-trimethyl-1-cyclohexene 
• 171504-26-0 5-tert-Butyldimethylsilyloxymethyl-1-phenylsulfonylmethyl-2,6,6-trimethylcyclohex-1-ene 
• 171504-38-4 (E)-5-tert-butyldimethylsiloxymethyl-1-<2-(1-methyl-2,5-cyclohexadien-1-yl)-ethen-1-yl>-2,6,6-trimethyl-1-cyclohexene 

Relevant academic research and scientific papers

The unexpected formation of bicyclo[2.2.1]heptane derivatives by Lewis acid-catalyzed transannular double cyclization

Attempted synthesis of the cyclooctanoid skeleton of taxane molecules, by an intramolecular Lewis acid catalyzed Hosomi-Sakurai cyclization of the allylsilane with the aldehyde moiety in 17, unexpectedly led to the formation of bicyclo[2.2.1]-heptane deri

Preparation of olefins and acetylenes via reductive elimination with Sml2-HMPA

Reaction of β-hydroxy or acetoxy sulfones with Sml2 in the presence of HMPA caused effectively reductive elimination to provide olefins. Treatment of enol phosphates, readily synthesized from β-hydroxy sulfones via keto sulfones, under the same conditions efficiently produced mono- and disubstituted acetylenes.