171504-26-0Relevant articles and documents
The unexpected formation of bicyclo[2.2.1]heptane derivatives by Lewis acid-catalyzed transannular double cyclization
Majo, Vattoly J.,Suzuki, Shuichi,Toyota, Masahiro,Ihara, Masataka
, p. 3375 - 3381 (2007/10/03)
Attempted synthesis of the cyclooctanoid skeleton of taxane molecules, by an intramolecular Lewis acid catalyzed Hosomi-Sakurai cyclization of the allylsilane with the aldehyde moiety in 17, unexpectedly led to the formation of bicyclo[2.2.1]-heptane deri
Preparation of olefins and acetylenes via reductive elimination with Sml2-HMPA
Ihara, Masataka,Suzuki, Shuichi,Taniguchi, Takahiko,Tokunaga, Yuji,Fukumoto, Keiichiro
, p. 9873 - 9890 (2007/10/02)
Reaction of β-hydroxy or acetoxy sulfones with Sml2 in the presence of HMPA caused effectively reductive elimination to provide olefins. Treatment of enol phosphates, readily synthesized from β-hydroxy sulfones via keto sulfones, under the same conditions efficiently produced mono- and disubstituted acetylenes.