320381-91-7

Upstream product

• 216978-35-7 Acetic acid 5-(tert-butyl-dimethyl-silanyloxymethyl)-2,6,6-trimethyl-cyclohex-1-enylmethyl ester 
• 216978-34-6 1-Acetoxymethyl-5-hydroxymethyl-2,6,6-trimethylcyclohex-1-ene 
• 318949-70-1 (Z)-5-tert-Butyldimethylsilyloxymethyl-1-[2-(1-methylcyclohexa-2,5-dien-1-yl)ethenyl]-2,6,6-trimethylcyclohex-1-ene 
• 318949-71-2 (Z)-5-Hydroxymethyl-1-[2-(1-methylcyclohexa-2,5-dien-1-yl)ethenyl]-2,6,6-trimethylcyclohex-1-ene 
• 171504-34-0 5-tert-butyldimethylsiloxymethyl-1-<2-hydroxy-2-(1-methyl-2,5-cyclohexadien-1-yl)-1-phenylsulfonylethyl>-2,6,6-trimethyl-1-cyclohexene 
• 171504-26-0 5-tert-Butyldimethylsilyloxymethyl-1-phenylsulfonylmethyl-2,6,6-trimethylcyclohex-1-ene 
• 171504-25-9 5-tetr-Butyldimethylsilyloxymethyl-1-phenylthiomethyl-2,6,6-trimethylcyclohex-1-ene 
• 171504-38-4 (E)-5-tert-butyldimethylsiloxymethyl-1-<2-(1-methyl-2,5-cyclohexadien-1-yl)-ethen-1-yl>-2,6,6-trimethyl-1-cyclohexene 
• 171504-24-8 [5-(tert-Butyl-dimethyl-silanyloxymethyl)-2,6,6-trimethyl-cyclohex-1-enyl]-methanol 
• 144066-82-0 Acetic acid 2-isopropenyl-3-methyl-but-2-enyl ester 
• 144067-40-3 Acetic acid 5-formyl-2,6,6-trimethyl-cyclohex-1-enylmethyl ester 

Relevant academic research and scientific papers

The unexpected formation of bicyclo[2.2.1]heptane derivatives by Lewis acid-catalyzed transannular double cyclization

Attempted synthesis of the cyclooctanoid skeleton of taxane molecules, by an intramolecular Lewis acid catalyzed Hosomi-Sakurai cyclization of the allylsilane with the aldehyde moiety in 17, unexpectedly led to the formation of bicyclo[2.2.1]-heptane deri

Assembly of bicycloheptane derivatives by two types of domino reaction

On treatment with titanium/IV) chloride, the allylsilane 1 readily cyclised by a domino-type process to give a spiro compound 6 as the main product, while the reaction of unsilylated 8 or 9 with tin(IV) chloride provided the aromatic products 7.