17257-79-3Relevant articles and documents
Iron-Catalyzed Epoxidation of Linear α-Olefins with Hydrogen Peroxide
Mao, Shuxin,Budweg, Svenja,Spannenberg, Anke,Wen, Xiaodong,Yang, Yong,Li, Yong-Wang,Junge, Kathrin,Beller, Matthias
, (2022/01/26)
The combination of Fe(OTf)2 with N-methyl bis(picolylamine) (Me-bpa) L7 enables epoxidation of linear olefins including terminal, internal, and cyclic ones, using hydrogen peroxide as terminal oxidant under mild conditions. In the presence of picolinic acid as additive improved yields of epoxides up to 75 % have been achieved.
Facile epoxidation of α,β-unsaturated ketones with cyclohexylidenebishydroperoxide
Jakka, Kavitha,Liu, Jinyun,Zhao, Cong-Gui
, p. 1395 - 1398 (2007/10/03)
Cyclohexylidenebishydroperoxide was successfully used as the oxygen source for the oxidation of α,β-unsaturated ketones for the first time. The corresponding epoxides were obtained in excellent yields under the Weitz-Scheffer reaction conditions.
TRANSFORMATION OF ACETYLOXIRANES TO THIIRANE ANALOGS
Bubel, O. N.,Tishchenko, I. G.,Stasevich, G. Z.,Veraksich, E. L.,Filich, E. R.
, p. 1082 - 1085 (2007/10/02)
A method for the synthesis of acetylthiiranes was developed; this method includes the conversion of acetyloxiranes to diethylketals, dealkoxylation of the latter, replacement of the oxygen atom of the oxirane ring by sulfur, and acidic hydrolysis of the ethoxyvinylthiirane to acetylthiiranes.