17424-68-9

Upstream product

• 7677-24-9 trimethylsilyl cyanide 
• 62-53-3 aniline 
• 98-86-2 acetophenone 
• 631-57-2 Acetyl cyanide 
• 4316-35-2 acetophenone dimethyl acetal 
• 630-18-2 tert-butyl isocyanide 
• 773837-37-9 sodium cyanide 
• 1749-19-5 phenyl(1-phenylethylidene)amine 
• 536-74-3 phenylacetylene 
• 143-33-9 sodium cyanide 
• 151-50-8 potassium cyanide 
• 142-04-1 aniline hydrochloride 
• 20102-12-9 2-hydroxy-2-phenylpropionitrile 
• 60-29-7 diethyl ether 

Downstream Products

• 613-91-2 acetophenone oxime 
• 612-71-5 1,3,5-triphenylbenzene 
• 779-54-4 (S)-N-phenyl-1-phenylethylamine 
• 380631-64-1 6-tert-butyl-3-[1-ethoxyiminoethyl]-4-hydroxy-1-phenylpyridin-2(1H)-one 
• 380632-94-0 3-[1-benzyloxyiminoethyl]-4-hydroxy-6-isopropyl-1-phenylpyridin-2(1H)-one 
• 380634-75-3 3-[1-ethoxyiminoethyl]-4-hydroxy-6-isopropyl-1-phenylpyridin-2(1H)-one 
• 380631-65-2 3-[1-allyloxyiminoethyl]-4-hydroxy-5-ethyl-1,6-diphenylpyridin-2(1H)-one 
• 380631-63-0 3-[1-benzyloxyiminoethyl]-4-hydroxy-5-ethyl-1,6-diphenylpyridin-2(1H)-one 
• 380631-71-0 3-[1-ethoxyiminoethyl]-5-ethyl-4-hydroxy-1,6-diphenylpyridin-2(1H)-one 
• 380631-68-5 3-[1-ethoxyiminoethyl]-4-hydroxy-5-methyl-1,6-diphenylpyridin-2(1H)-one 
• 380634-51-5 3-[1-allyloxyiminoethyl]-4-hydroxy-1,6-diphenylpyridin-2(1H)-one 
• 380631-66-3 3-[1-benzyloxyiminoethyl]-4-hydroxy-1,6-diphenylpyridin-2(1H)-one 
• 380631-61-8 3-[1-ethoxyiminoethyl]-4-hydroxy-1,6-diphenylpyridin-2(1H)-one 
• 503428-80-6 4-hydroxy-3-(1-methoxyiminoethyl)-1,6-diphenylpyridin-2(1H)-one 

Relevant academic research and scientific papers

A Discrete Tetrahedral Indium Cage as an Efficient Heterogeneous Catalyst for the Fixation of CO2 and the Strecker Reaction of Ketones

A discrete tetrahedral indium cage, {[In12(μ3-OH)4(HCO2)24(tcma)4]} (In12-GL), was synthesized solvothermally by the reaction of indium nitrate with the tripodal tricarboxylic ac

Tunable catalytic activity of solid solution metal-organic frameworks in one-pot multicomponent reactions

The aim of this research is to establish how metal-organic frameworks (MOFs) composed of more than one metal in equivalent crystallographic sites (solid solution MOFs) exhibit catalytic activity, which is tunable by virtue of the metal ions ratio. New MOF

High pressure mediated three component Strecker synthesis of α-aminonitriles from ketones, aromatic amines and trimethylsilyl cyanide

High pressure (600 MPa) reaction conditions, in the absence of a catalyst, have proved to be a powerful way to stimulate the three component Strecker reaction synthesis of α-aminonitriles in high yields. Examples of two types of double Strecker reactions were also described.

Main-chain organometallic microporous polymers bearing triphenylene-tris(N- heterocyclic carbene)-gold species: Catalytic properties

Two triphenylene-based tris(N-heterocyclic carbene)-gold-acetylide main-chain organometallic microporous polymers (MOMPs) were obtained and fully characterized. Both materials show spherical shapes, and their size is highly dependent on the type of acetyl

Cuboctahedral [In36(μ-OH)24(NO3)8(Imtb)24]MOF with Atypical Pyramidal Nitrate Ion in SBU: Lewis Acid-Base Assisted Catalysis and Nanomolar Sensing of Picric Acid

A robust and multifunctional cuboctahedral [In36(μ-OH)24(NO3)8(Imtb)24] MOF (In(Imtb)-MOF) with an atypical pyramidal nitrate ion-containing hitherto unknown SBU core [In9(μ-OH)6(NO3)] is reported. The intra- and interlayer nitrate ions adopt pyramidal an

From Zn(II)-Carboxylate to Double-Walled Zn(II)-Carboxylato Phosphate MOF: Change in the Framework Topology, Capture and Conversion of CO2, and Catalysis of Strecker Reaction

The ligand H2L has been built by linking an imidazole moiety to the 5-position of isophthalic acid. It forms two types of porous frameworks, {[Zn(L)]·2DMF·2H2O}n (1) and {[(CH3)2NH2][Znsub

Cu/Ni-doped sulfated zirconium oxide immobilized on CdFe2O4 NPs: a cheap, sustainable and magnetically recyclable inorgano-catalyst for the efficient preparation of α-aminonitriles in aqueous media

Abstract: A new multifunctional bimetallic nanocatalyst was prepared by immobilization of Cu/Ni-doped sulfated zirconium oxide on magnetic cadmium ferrite (CdFe2O4@SiO2@ZrO2/SO42?/Cu/Ni) and used as an efficient recyclable catalyst for one-pot as well as stepwise preparation of α-aminonitriles under mild conditions. The magnetic nanocatalyst was characterized by FTIR, TGA, VSM, XRD, EDX, FE-SEM, and TEM analyses. Also, the surface acidity of the catalyst was measured by pyridine adsorption assay. The catalyst possesses various active sites which could catalyst a variety of aromatic and aliphatic aldehydes to the corresponding α-amionitriles under moderate to high yields in the presence of aniline. Furthermore, transformation of ketones to the desired α-amionitriles and some bis-aminonitriles was also performed by this method. The catalyst could be readily recovered from the reaction mixture and reused for several times without significant loss of activity. Graphic abstract: A general and efficient method has been developed for transformation of a variety of aliphatic, aromatic aldehydes and ketones to the corresponding α-aminonitriles using a multifunctional recyclable CdFe2O4@SiO2@ZrO2/SO42?/Cu/Ni nanocatalyst.[Figure not available: see fulltext.]

A microporous metal-organic framework catalyst for solvent-free strecker reaction and CO2 fixation at ambient conditions

The self-assembly of zinc(II) acetate tetrahydrate, a flexible tetrapyridyl ligand, tetrakis(3-pyridyloxymethylene)methane (3-tpom), a bent dicarboxylic acid, and 4,4′-(dimethylsilanediyl)bis- benzoic acid (H2L) under solvothermal conditions ha

Synthesis of α-Aminonitriles and 5-Substituted 1H-Tetrazoles Using an Efficient Nanocatalyst of Fe3O4@SiO2–APTES-supported Trifluoroacetic Acid

Fe3O4@SiO2–APTES-supported trifluoroacetic acid nanocatalyst was used for the one-pot synthesis of α-aminonitriles via a three-component reaction of aldehydes (or ketones), amines, and sodium cyanide. This method produced a high yield of 75–96% using only a small amount of the catalyst (0.05?g) in EtOH at room temperature. The catalyst was also employed for the synthesis of 5-substituted 1H-tetrazoles from nitriles and sodium azide in EtOH at 80°C. The tetrazoles were produced with good-to-excellent yields in a short reaction time of 4?h. Both synthetic methods were carried out in the absence of an organic volatile solvent. Because the supported trifluoroacetic acid generated a solid acid on the surface, thus the acid corrosiveness was not a serious challenge. This heterogeneous nanocatalyst was magnetically recovered and reused several times without significant loss of catalytic activity.

Gallic acid-functionalized magnetic nanoparticles: a convenient and green approach for synthesis of α-aminonitriles under solvent-free conditions

Abstract: Gallic acid-coated magnetic nanoparticles were efficiently prepared, characterized by Fourier transform infrared spectroscopy, X-ray diffraction, vibrating sample magnetometry, scanning electron microscopy, and transmission electron microscopy, and employed as an environmentally friendly and recyclable catalyst for one-pot synthesis of three-component reaction via Strecker reaction, incorporating aldehydes/ketones, amines, and trimethylsilyl cyanides under solvent-free conditions. Operational simplicity, product purity, natural resources and reusability of the catalyst are considered as evident features of this protocol which will hopefully develop into an inexpensive, efficient, and clean strategy for the synthesis of α-aminonitriles. Graphical abstract: [Figure not available: see fulltext.].