17432-52-9

Upstream product

• 536-74-3 phenylacetylene 
• 88-05-1 2,4,6-trimethylaniline 
• 98-86-2 acetophenone 

Downstream Products

• 1621182-12-4 N-(2,4,6-trimethylphenyl)-N-(1-phenylvinyl)-N-[dimethyl(phenyl)]silylamine 
• 1621182-13-5 N-(2,4,6-trimethylphenyl)-N-{2-[dimethyl(phenyl)]silyl-1-phenylvinyl}-N-[dimethyl-(phenyl)]silylamine 
• 1349171-48-7 (E)-2,4,6-trimethyl-N-{1-[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]ethylidene}aniline 

Relevant academic research and scientific papers

Coordination chemistry of gold with: N -phosphine oxide-substituted imidazolylidenes (POxIms)

N-Phosphine oxide-substituted imidazolylidenes (POxIms) have been employed as heteroditopic ligands towards gold centres. Both bis-carbene and mono-carbene gold(i) complexes have been obtained, depending on the steric bulk of the employed POxIm ligand. Ox

A Dinuclear Au(I) Complex with a Pyrene-di-N-heterocyclic Carbene Linker: Supramolecular and Catalytic Studies

A digold(I) complex with a pyrene-di-N-heterocyclic carbene ligand has been obtained and fully characterized. The host-guest properties of the complex were studied in chloroform with a series of polycylic aromatic hydrocarbons (PAHs), and the association

Strongly Coordinating Ligands to Form Weakly Coordinating Yet Functional Organometallic Anions

Weakly coordinating anions (WCAs) are generally tailored to act as spectators with little or no function. Here we describe the implementation of strongly coordinating dianionic carboranyl N-heterocyclic carbenes (NHCs) to create organometallic -ate comple

Catalytic Arylative Endo Cyclization of Gold Acetylides: Access to 3,4-Diphenyl Isoquinoline, 2,3-Diphenyl Indole, and Mesoionic Normal NHC–Gold Complex

3,4-Diphenyl isoquinoline and 2,3-diphenyl indole are readily accessed by catalytic selective bis-arylative endo cyclization of gold acetylides. The synthetic approach could be also extended to prepare six-membered mesoionic NHC complex, which could furth

Synthesis of an anionic Au(I) hydroamination precatalyst supported by charged hydrido-carboranyl phosphine ligands

Herein is reported the synthesis of an anionic gold complex bearing two charged hydrido carboranyl phosphine ligands. The compound is fully characterized by multinuclear NMR spectroscopy, high resolution mass spectrometry, as well as a single crystal X-ra

Ferrocenyl-Imidazolylidene Ligand for Redox-Switchable Gold-Based Catalysis. A Detailed Study on the Redox-Switching Abilities of the Ligand

An imidazolium salt with a fused benzoferrocenyl was synthesized. This compound was used as an N-heterocyclic carbene (NHC) precursor, and the related ferrocenyl-imidazolylidene complexes Fc-NHC-MLn (MLn = IrCl(COD), IrCl(CO)2/

Dialkyl(1,3-diarylimidazolin-2-ylidenamino)phosphines: Strongly Electron-Donating, Buchwald-Type Phosphines

The synthesis and properties of a series of strongly electron-donating, sterically demanding dialkyl(1,3-diarylimidazolin-2-ylidenamino)phosphines (IAPs) are reported. Determination of the TEP values shows that the bulky IAPs are better donor ligands than

Gold(I) complexes bearing ring-fused benzoxazine-derived triazolylidenes and their use in C–N bond-forming processes

We report the synthesis and full characterization of a novel series of ring-fused benzoxazine-derived triazolium salts (1a–c) and their corresponding triazolylidene gold(I) complexes (2a–c). All new compounds were fully characterized by means of 1H and 13C NMR spectroscopy, elemental analyses, and mass spectroscopy and in the case of triazoliums 1a and 1b by single-crystal X-ray diffraction. The new triazolylidene gold complexes (2a–c) were tested as precatalysts in the hydroamination and hydrohydrazination of terminal alkynes employing aniline derivatives and hydrazine as nitrogen sources, respectively.

Synthesis and Catalytic Applications of Multinuclear Gold(I)-1,2,3-Triazolylidene Complexes

A series of mono- to trinuclear gold(I) complexes (1–3) supported by oxo-functionalized 1,2,3-triazolylidenes have been prepared. All new compounds were fully characterized by means of 1H and 13C NMR spectroscopy, elemental analyses, and in the case of complexes 1 and 2 by x-ray diffraction. The catalytic performance of the new triazolylidene gold complexes was tested in several hydroelementation and cyclization processes employing a variety of alkynes as starting materials. According to the overall results, the trinuclear complex 3 displayed the highest catalytic activity in all processes, providing good to excellent yields under mild reaction conditions.

Syntheses of Triangular Gold Complexes and Their Applications in Hydroamination Reaction

Triangular all-metal complexes have aroused our research interest due to their unique structural and properties. Herein, through the facile reduction of μ3-oxo complex [μ3-O(PPh3Au)3]+BF4s