175025-05-5

Basic information

• Product Name: 2-phenylpyrrolidino[3',4':1,2][60]fullerene
• Synonyms: 2-phenylpyrrolidino[3',4':1,2][60]fullerene
• CAS NO: 175025-05-5
• Molecular Weight: 839.826
• Mol File: 175025-05-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-phenylpyrrolidino[3',4':1,2][60]fullerene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenylpyrrolidino[3',4':1,2][60]fullerene(175025-05-5)
• EPA Substance Registry System: 2-phenylpyrrolidino[3',4':1,2][60]fullerene(175025-05-5)

Safety Data

• Hazardous Substances Data: 175025-05-5(Hazardous Substances Data)

Upstream product

• 56-41-7 L-alanin 
• 100-52-7 benzaldehyde 
• 99685-96-8 fullerene-C₆₀ 
• 100-44-7 benzyl chloride 
• 56-40-6 glycine 
• 56-34-8 tetraethylammonium chloride 
• 108-88-3 toluene 
• 50-00-0 formaldehyd 
• 2835-06-5 phenylglycin 

Downstream Products

• 232284-42-3 N-(2,4-dinitrophenyl)-2-phenylpyrrolidino[3',4':1,2][60]fullerene 

Relevant articles and documents

Cycloadditions to [60]fullerene using microwave irradiation: A convenient and expeditious procedure

Several Diets-Alder and 1,3-dipolar cycloadditions to C60 were performed, under microwave irradiation, in a modified domestic microwave oven and a focused microwave reactor. Reactions proceed within minutes to afford the respective cycloadducts in similar or increased yields related to the described methods by conventional heating. This methodology simplifies the procedure and overcomes the drawbacks resulting from the long reaction times required under classical heating conditions.

The first crown ether-bearing [60]Fulleropyrrolidine: Synthesis and regulation of absorption spectrum by ions binding

A monoadduct of [60]Fulleropyrrolidine having a 15-crown-5 structure has been prepared and characterised. It is found that the absorption spectrum of this crowned fullerene can be regulated hypsochromically by metal ions complexation.

Synthesis of fulleropyrrolidines through the reaction of [60]fullerene with quaternary ammonium salts and amino acids

The reactions of [60]fullerene with amino acids and quaternary ammonium salts in toluene afforded two fulleropyrrolidine derivatives. One fulleropyrrolidine derivative contained a RCH moiety originating from quaternary ammonium salts through C-N bond cleavages and other fulleropyrrolidine derivatives contained a PhCH moiety originating from toluene through C-H bond cleavage. By using chlorobenzene instead of toluene as solvent, only one fulleropyrrolidine derivative containing a RCH moiety was obtained in the reactions.