175788-33-7

Basic information

• Product Name: Benzenemethanol, a-(1-ethenylbutyl)-
• CAS NO: 175788-33-7
• Molecular Formula: C13H18O
• Molecular Weight: 190.285
• Mol File: 175788-33-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(1-ethenylbutyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(1-ethenylbutyl)-(175788-33-7)
• EPA Substance Registry System: Benzenemethanol, a-(1-ethenylbutyl)-(175788-33-7)

Safety Data

• Hazardous Substances Data: 175788-33-7(Hazardous Substances Data)

Upstream product

• 28000-59-1 α,α-diiodotoluene 
• 3761-92-0 n-hexylmagnesium bromide 
• 100-52-7 benzaldehyde 
• 592-41-6 1-hexene 
• 98-88-4 benzoyl chloride 
• 37658-00-7 (E)-1-chloro-2-hexene 
• 928-95-0 (E)-2-Hexen-1-ol 
• 60982-98-1 (E)-hex-2-enyl-tributylstannane 

Relevant articles and documents

Direct Preparation of Allylic Zirconium Reagents from Zirconocene-Olefin Complexes and Alkenes

A novel method for preparation of allylic zirconium reagents directly from 1-alkenes via zirconoceneolefin complex has been developed. Selective transfer of the hydride of zirconocene allyl hydride complex, a tautomer of zirconocene-olefin complex, to diisopropyl ketone generates the corresponding zirconocene alkoxide allyl. The allylic zirconium reagents formed effects stereoselective allylation of aldehyde at 25 °C and -78 °C to provide syn- and anti-homoallyl alcohols, respectively. The anti-isomer is formed via a six-membered chair transition state under kinetic control. The syn-selectivity can be rationalized by considering isomerization of the anti-adduct by a retroallylation process.

Transformation of zirconocene-olefin complexes into zirconocene allyl hydride and their use as dual nucleophilic reagents: Reactions with acid chloride and 1,4-diketone

Zirconocene-olefin complexes Cp2Zr(H2C=CHR), prepared in benzene-THF at 0 °C, react with acid chlorides to provide homoallylic alcohols. The key is an equilibrium between the zirconocene-olefin complexes and the corresponding zircono

Barbier-type carbonyl-allylation with allyl compounds and SnCl2 in the presence of PdCl2[PPh2(m-C6H4SO 3Na)]2 under two-phase conditions

The hydrophilic palladium complex efficiently catalyzes the allylation of carbonyl compounds with allyl chlorides or allyl alcohols and SnCl2 under aqueous-organic biphase conditions, which allow us easily to separate the product and to recover the organic solvent from the reaction mixture.