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17581-85-0

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17581-85-0 Usage

Uses

3-(4-Methoxyphenyl)-2-propen-1-ol is a useful reagent.

Check Digit Verification of cas no

The CAS Registry Mumber 17581-85-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,5,8 and 1 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 17581-85:
(7*1)+(6*7)+(5*5)+(4*8)+(3*1)+(2*8)+(1*5)=130
130 % 10 = 0
So 17581-85-0 is a valid CAS Registry Number.
InChI:InChI=1/C10H12O2/c1-12-10-6-4-9(5-7-10)3-2-8-11/h2-7,11H,8H2,1H3/b3-2+

17581-85-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name (E)-3-(4-methoxyphenyl)prop-2-en-1-ol

1.2 Other means of identification

Product number -
Other names allylic alcohol for 1a

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:17581-85-0 SDS

17581-85-0Relevant articles and documents

NH2-MIL-125(Ti)-derived porous cages of titanium oxides to support Pt-Co alloys for chemoselective hydrogenation reactions

Gu, Zhizhi,Chen, Liyong,Li, Xuezhao,Chen, Lin,Zhang, Yingyue,Duan, Chunying

, p. 2111 - 2117 (2019)

The change of atom density induced structural collapse in the transformation process from metal-organic frameworks (MOFs) to their inorganic counterparts is a major challenge to the achievement of porous hollow structures. Herein, we develop an amino acid-mediated strategy for transformation of NH2-MIL-125(Ti) to successfully synthesize well-defined porous cages of titanium oxides (PCT) due to sheets serving as structural scaffolds. On this basis, PCT supported Pt-based nanoparticles are generated via a similar synthetic route, and are utilized to study the selective hydrogenation of carbonyl groups in α,β-unsaturated aldehydes, benefiting from the specific structures of PCT and tunable electronic structures of Pt mainly affected by doping with metal species such as Co. In this case, Pt-Co/PCT composites give 96% selectivity for cinnamyl alcohol at 100% conversion of cinnamaldehyde under 0.2 MPa H2 and 80 °C for 3 h. This research would offer a promising strategy for important organic transformations in academic and industrial research to selectively synthesize high-value-added products.

Copper(i) pyrimidine-2-thiolate cluster-based polymers as bifunctional visible-light-photocatalysts for chemoselective transfer hydrogenation of α,β-unsaturated carbonyls

Zhang, Meng Juan,Young, David James,Ma, Ji Long,Shao, Guo Quan

, p. 14899 - 14904 (2021/05/19)

The photoinduced chemoselective transfer hydrogenation of unsaturated carbonyls to allylic alcohols has been accomplished using cluster-based MOFs as bifunctional visible photocatalysts. Assemblies of hexanuclear clusters [Cu6(dmpymt)6] (1, Hdmpymt = 4,6-dimethylpyrimidine-2-thione) as metalloligands with CuI or (Ph3P)CuI yielded cluster-based metal organic frameworks (MOFs) {[Cu6(dmpymt)6]2[Cu2(μ-I)2]4(CuI)2}n (2), {[Cu6(dmpymt)6]2[Cu2(μ-I)2]4}n (3), respectively. Nanoparticles (NPs) of 2 and 3 served both as photosensitizers and photocatalysts for the highly chemoselective reduction of unsaturated carbonyl compounds to unsaturated alcohols with high catalytic activity under blue LED irradiation. The photocatalytic system could be reused for several cycles without any obvious loss of efficiency.

Intramolecular Sakurai Allylation of Geminal Bis(silyl) Enamide with Indolenine. A Diastereoselective Cyclization to Form Functionalized Hexahydropyrido[3,4- b]Indole

Chen, Yi,Gao, Lu,Song, Xuanyi,Song, Zhenlei

, p. 124 - 128 (2021/01/13)

A fluoride-promoted intramolecular Sakurai allylation of geminal bis(silyl) enamide with indolenine has been developed. The reaction facilitates an efficient cyclization to give hexahydropyrido[3,4-b]indoles in good yields with high diastereoselectivity. The resulted cis, trans-stereochemistry further enables the ring-closing metathesis (RCM) reaction of two alkene moieties, giving a tetracyclic N-hetereocycle widely found as the core structure in akuammiline alkaloids.

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