176776-60-6

Basic information

• Product Name: 2,2''-(1E,1''E)-Trans (+/-)-Cyclohexane-1,2-Diylbis(Azan-1-Yl-1-Ylidene)Bis(Methan-1-Yl-1-Ylidene)Diphenol
• Synonyms: 2,2''-(1E,1''E)-Trans (+/-)-Cyclohexane-1,2-Diylbis(Azan-1-Yl-1-Ylidene)Bis(Methan-1-Yl-1-Ylidene)Diphenol
• CAS NO: 176776-60-6
• Molecular Formula: C20H22N2O2
• Molecular Weight: 322.40088
• Mol File: 176776-60-6.mol
• Article Data: 52

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,2''-(1E,1''E)-Trans (+/-)-Cyclohexane-1,2-Diylbis(Azan-1-Yl-1-Ylidene)Bis(Methan-1-Yl-1-Ylidene)Diphenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2''-(1E,1''E)-Trans (+/-)-Cyclohexane-1,2-Diylbis(Azan-1-Yl-1-Ylidene)Bis(Methan-1-Yl-1-Ylidene)Diphenol(176776-60-6)
• EPA Substance Registry System: 2,2''-(1E,1''E)-Trans (+/-)-Cyclohexane-1,2-Diylbis(Azan-1-Yl-1-Ylidene)Bis(Methan-1-Yl-1-Ylidene)Diphenol(176776-60-6)

Safety Data

• Hazardous Substances Data: 176776-60-6(Hazardous Substances Data)

Usage

Molecular structure

2,2''-(1E,1''E)-Trans (+/-)-Cyclohexane-1,2-Diylbis(Azan-1-Yl-1-Ylidene)Bis(Methan-1-Yl-1-Ylidene)Diphenol has a complex molecular structure with a cyclohexane-1,2-diylbis group in the center, two azan-1-yl-1-ylidene groups, two methan-1-yl-1-ylidene groups, and two diphenol groups attached to it.

Potential applications

Due to its complex structure, this compound may have potential applications in organic synthesis, catalysis, or as a ligand for metal complexes. Further research and studies are needed to determine its exact properties and uses.

Stereochemistry

The (+/-) notation indicates that the compound could exist in both enantiomeric forms (mirror images), which may have different properties and reactivities.

Azan-1-yl-1-ylidene groups

These nitrogen-containing groups may contribute to the compound's ability to form coordination bonds with metal ions, potentially making it a useful ligand in metal complex formation.

Methan-1-yl-1-ylidene groups

These groups may provide additional steric and electronic effects, influencing the compound's reactivity and stability.

Diphenol groups

The presence of two diphenol groups suggests that the compound may have antioxidant properties or be involved in redox reactions.

Further research needed

The specific properties and potential uses of this compound would need to be further studied and determined through experimental and computational methods.

Upstream product

• 90-02-8 salicylaldehyde 
• 694-83-7 rac-diaminocyclohexane 
• 21436-03-3 (S,S)-1,2-diaminocyclohexane 
• 89-95-2 2-methyl-benzyl alcohol 
• 32044-22-7 (R,R)-1,2-diammoniumcyclohexane mono-(+)-tartrate salt 
• 110-83-8 cyclohexene 
• 1121-22-8 trans-1,2-Diaminocyclohexane 
• 20439-47-8 (1R,2R)-1,2-diaminocyclohexane 
• 1194-98-5 2,5-Dihydroxybenzaldehyde 
• 32044-22-7 (R,R)-1,2-diaminocyclohexane tartrate 
• 32044-22-7 (1R,2R)-1,2-diaminocyclohexane tartrate 
• 10027-80-2 (1R,2R)-1,2-dicyclohexane-1,2-diamine dihydrochloride 
• 4383-05-5 2-hydroxy-3-methoxybenzyl alcohol 
• 1436-59-5 cis-cyclohexane-1,2-diamine 

Downstream Products

• 1537890-05-3 (R,R)-1,2-cyclohexylenediamino-di-(R,R)-[(2-hydroxyphenyl)-methylphosphonic acid] 
• 1537890-09-7 tetraisopropyl (R,R)-1,2-cyclohexylenediamino-di-(R,R)-[(2-hydroxyphenyl)methylphosphonate] 
• 1537890-07-5 tetraethyl (R,R)-1,2-cyclohexylenediamino-di-(R,R)-[(2-hydroxyphenyl)methylphosphonate] 
• 1537890-04-2 tetramethyl (R,R)-1,2-cyclohexylenediamino-di-(R,R)-[(2-hydroxyphenyl)methylphosphonate] 

Relevant articles and documents

Chiral anionic binuclear zinc complexes based on diaminocyclohexane ligand and their in vitro antiproliferative studies

Two novel binuclear chiral anionic Zn(II) complexes, [Zn 2LCl3]- (C2H5) 3N+ 1 and [Zn2L(CH3COO) 3]- (C2H5)3N+ 2 counterbalanced by triethyl ammonium cation, have been synthesized from ligand, 2,2′-((1E,1′E)-((1R,2R)-cyclohexane-1,2- diylbis(azanylylidene))bis(methanylylidene))dipheno, H2L. The ligand, H2L and its complexes are characterized by elemental analyses, IR, 1H and 13C NMR, ESI-MS, electronic and thermal studies. Complex 1 has been additionally characterized by single crystal X-ray diffraction studies and confirmed a slightly distorted tetragonal pyramid coordination environment in which both zinc atoms are five coordinated by two imine nitrogen atoms, two oxygen atoms and one chloride ion located at the polyhedron apex. Ligand, H2L and its Zn(II) complexes have been subjected to antiproliferative studies against HCT p53 wild type as well as HCT p53 null cell lines, and the results suggest complexes to be an effective antiproliferative agent against these cancer cell lines in comparison to ligand, H2L. Furthermore, DNA fragmentation studies revealed that Zn(II) complexes induce significant p53 independent apoptosis in cancer cell lines.

Synthesis and spectroscopic study of Schiff bases derived from trans-1,2-diaminocyclohexane. Deuterium isotope effect on 13C chemical shift

The proton transfer in the intramolecular hydrogen bond in a series of Schiff bases derivatives of aromatic orthohydroxyaldehydes and trans-1,2-diaminocyclohexane has been studied by means of IR, UV-Vis, 1H and 13C NMR spectroscopies. The measurement of deuterium isotope effect on 13C chemical shift suggests that the proton transfer equilibria in both salicylidene moieties are not independent. Substitution of H by D in one hydrogen bond shifts the proton transfer equilibrium in one direction in this moiety, while in the opposite direction in the other.

Trans-(±)-N,N′-bis(salicylidene)-1,2-cyclohexanediamine

The title compound, C20H22N2O2, is C2 symmetric with the two N atoms bonded to salicylidene groups which are trans with respect to the cyclohexane ring.

Multi-wavelength spectrophotometric determination of acidity constants of some salicylaldimine derivatives

The acidity constants of 9 synthesized derivatives of Schiff base in dimethylformamide/water and ethanol/water (25:75 v/v) at 25 C and an ionic strength of 0.1 M have been determined spectrophotometrically. All of the spectrophotometric data as pure spect

Two Schiff base ligands derived from 1,2-diaminocyclohexane

The crystal structures of the free ligands 2,2′-[(1,2-cyclohexanediyl)bis(nitrilomethylidyne)]bisphenol, C20H22N2O2, (I), and 2,2′-[(1,2-cyclohexanediyl)bis-(nitriloethylidyne)]bisphenol, C22H26

Chiral porous poly(ionic liquid)s: Facile one-pot, one-step synthesis and efficient heterogeneous catalysts for asymmetric epoxidation of olefins

Ionic liquids are potential media/solvents for asymmetric synthesis when combined with chiral catalysts, while most reported catalysts are homogenous, making them difficult to separate from the reaction systems. Herein, chiral porous poly(ionic liquid)s (

Polymerization of Ethylene in the Presence of Titanium(IV), Zirconium(IV), and Vanadium(V) Coordination Compounds with Salen Ligands

Abstract: Coordination compounds of titanium(IV), zirconium(IV), and vanadium(V) with chiral salen ligands have been obtained and characterized, and their catalytic activity in the polymerization reaction of ethylene has been studied. It has been shown that in the presence of polymethylaluminoxane as a cocatalyst, the activity of the titanium-containing catalyst system reaches 944 kgPE mol(Ti)?1 h?1 and leads to the preparation of ultrahigh-molecular-weight polyethylene.