17687-47-7

Basic information

• Product Name: Ethanone, 1-[4-(methylamino)phenyl]- (9CI)
• Synonyms: Ethanone, 1-[4-(methylamino)phenyl]- (9CI);1-[4-(methylamino)phenyl]ethanone;p-Methylaminoacetophenone;4-Acetyl-N-methylaniline;4-N-Methylaminoacetophenone;4'-(Methylamino)acetophenone;N-Methyl-4-acetylaniline;4-Acetyl-N-methylaniline 97%
• CAS NO: 17687-47-7
• Molecular Formula: C₉H₁₁NO
• Molecular Weight: 149.18974
• Product Categories: ACETYLGROUP
• Mol File: 17687-47-7.mol
• Article Data: 38

Chemical Properties

• Melting Point: 103-107 °C
• Boiling Point: 281.7±23.0 °C(Predicted)
• Appearance: White to pale brown/Solid
• Density: 1.062±0.06 g/cm3(Predicted)
• Storage Temp.: Inert atmosphere,Room Temperature
• PKA: 1.96±0.12(Predicted)
• CAS DataBase Reference: Ethanone, 1-[4-(methylamino)phenyl]- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-(methylamino)phenyl]- (9CI)(17687-47-7)
• EPA Substance Registry System: Ethanone, 1-[4-(methylamino)phenyl]- (9CI)(17687-47-7)

Safety Data

• Hazard Codes: Xi
• Statements: 43
• Safety Statements: 36/37
• WGK Germany: 2
• Hazardous Substances Data: 17687-47-7(Hazardous Substances Data)

Usage

Chemical Properties

White to tan solid

Purification Methods

This herbicide crystallises from H2O. The 4-acetyl-N,N-dimethylaniline derivative forms colourless plates also from H2O with m 58-59o. [Klingel Chem Ber 18 2694 1885, Staudinger & Kon Justus Liebigs Ann Chem 384 111 1911, Beilstein 14 H 47, 14 I 366.]

Upstream product

• 50-00-0 formaldehyd 
• 99-92-3 p-aminobenzophenone 
• 99-90-1 para-bromoacetophenone 
• 74-89-5 methylamine 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 84984-24-7 1-(p-acetylphenyl)-3-cyano-1-methyltriazene 
• 82834-23-9 p-(N-methyl-N-p-tolylsulphonylamino)acetophenone 
• 74378-50-0 C₂₇H₂₅NOP⁽¹⁺⁾*I^(1-) 
• 74-88-4 methyl iodide 
• 77-78-1 dimethyl sulfate 
• 67014-02-2 4-acetylbenzamide 
• 67-56-1 methanol 
• 100-19-6 (4-nitrophenyl)ethanone 
• 75-52-5 nitromethane 

Downstream Products

• 130600-02-1 2,2-Dimethyl-N-[2-[3-(4-methylamino-phenyl)-3-oxo-propionyl]-3-(tetrahydro-pyran-2-yloxy)-phenyl]-propionamide 
• 1252037-82-3 4-(1H-indol-2-yl)-N-methylbenzenenamine 
• 1248590-89-7 1-(4-((1H-benzo[d]imidazol-6-yl)(methyl)amino)phenyl)ethanone 
• 1612838-26-2 C₁₆H₁₅NO₃ 
• 102877-42-9 N-methyl-4-vinylaniline 
• 60711-16-2 N-(4-acetylphenyl)-N-methylformamide 
• 4150-37-2 N,N-dimethyl-4-ethylaniline 
• 2124-31-4 4'-dimethylaminoacetophenone 

Relevant articles and documents

Conformational Studies by Dynamic Nuclear Magnetic Resonance Spectroscopy. Part 19. Substituent Effect upon the Rotational Barrier of Alkylanilines

The low-temperature n.m.r. spectra at the 13C frequency (25.16 MHz) showed the non-equivalence of the ortho-and meta-carbons in a number of substituted N-alkylanilines.Line-shape analysis, or measurement at the coalescence temperature, yielded the free en

Photoinduced Hydroarylation and Cyclization of Alkenes with Luminescent Platinum(II) Complexes

Photoinduced hydroarylation of alkenes is an appealing synthetic strategy for arene functionalization. Herein, we demonstrated that aryl radicals generated from electron-deficient aryl chlorides/bromides could be trapped by an array of terminal/internal aryl alkenes in the presence of [Pt(O^N^C^N)] under visible-light (410 nm) irradiation, affording anti-Markovnikov hydroarylated compounds in up to 95 % yield. Besides, a protocol for [Pt(O^N^C^N)]-catalyzed intramolecular photocyclization of acrylanilides to give structurally diverse 3,4-dihydroquinolinones has been developed.

A novel and unusual method for C[sbnd]N bond formation between benzene ring and various amines

A new approach to form C[sbnd]N bond without metal catalysis was developed. 4-acetylbenzoyl isocyanate reacted with various amines through a mild method to form C[sbnd]N bond. This reaction was amenable to scale-up and it afforded the corresponding products with good to excellent yields and tolerates a wide range of functional groups.