17734-31-5

Upstream product

• 6529-51-7 2-(4-methylphenyl)ethyl bromide 
• 109-89-7 diethylamine 
• 4186-14-5 1-(2-(trimethylsilyl)ethynyl)toluene 
• 624-31-7 4-tolyl iodide 
• 1377187-54-6 4,4,5,5-tetramethyl-2-(2-p-tolylvinyl)[1,3,2]dioxaborolane 
• 766-97-2 4-n-methylphenylacetylene 
• 699-02-5 4-Methylphenethyl alcohol 
• 6749-78-6 4-methylphenylmagnesium iodide 
• 4294-57-9 para-methylphenylmagnesium bromide 

Relevant academic research and scientific papers

Formal anti-markovnikov hydroamination of terminal aryl alkynes with pinacolborane and hydroxylamines via Zr/Cu sequential catalysis

We have explored a novel dry plasma process for the fabrication of electrodes on Nafion surfaces. Nanosized pillar structures were prepared through argon ion (Ar+) plasma treatment. The shear strengths of Au electrodes on plasma-treated Nafion surfaces were investigated. We found that the maximum shear strength (1.08 MPa) of Au-Nafion was observed under the optimal conditions (8 min, 100 W, 5 Pa, Ar+). Finally, we successfully prepared strongly bonded Au electrodes on Nafion through plasma surface treatment without using a wet plating process.

Arylsulfonate esters in solid phase organic synthesis. I. Cleavage with amines, thiolate, and imidazole

The arylsulfonate ester functionality connecting an alkyl chain to a polystyrene resin is cleaved with neat volatile primary or secondary amines to give secondary or tertiary amines, respectively, in high yields and purity. Non-volatile secondary amines, thiols, and imidazole also cleave the alkyl chain efficiently to afford the expected products which can be readily purified by an ion-exchange resin work-up method.