17849-31-9

Basic information

• Product Name: alpha-chloro-p-nitro-hydrocinnamonitril
• Synonyms: ALPHA-CHLORO-4-NITROHYDROCINNAMONITRILE;alpha-chloro-p-nitro-hydrocinnamonitril
• CAS NO: 17849-31-9
• Molecular Formula: C₉H₇ClN₂O₂
• Molecular Weight: 210.61708
• Mol File: 17849-31-9.mol
• Article Data: 7

Chemical Properties

• Melting Point: 111-112 °C
• Boiling Point: 391.1°Cat760mmHg
• Flash Point: 190.3°C
• Appearance: /
• Density: 1.352g/cm³
• Vapor Pressure: 2.53E-06mmHg at 25°C
• Refractive Index: 1.578
• CAS DataBase Reference: alpha-chloro-p-nitro-hydrocinnamonitril(CAS DataBase Reference)
• NIST Chemistry Reference: alpha-chloro-p-nitro-hydrocinnamonitril(17849-31-9)
• EPA Substance Registry System: alpha-chloro-p-nitro-hydrocinnamonitril(17849-31-9)

Safety Data

• Hazardous Substances Data: 17849-31-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H7ClN2O2/c10-8(6-11)5-7-1-3-9(4-2-7)12(13)14/h1-4,8H,5H2/t8-/m1/s1

Upstream product

• 14368-49-1 p-nitrobenzenediazonium 
• 107-13-1 acrylonitrile 
• 100-01-6 4-nitro-aniline 
• 100-16-3 4-nitrophenylhydrazone 
• 92491-67-3 tert-butyl 2-(4-nitrophenyl)hydrazine-1-carboxylate 
• 17672-27-4 4-hydrazinobenzonitrile 
• 1354828-66-2 tert-butyl 2-(4-cyanophenyl)diazene-1-carboxylate 
• 92722-14-0 tert-butyl 2-(4-nitrophenyl)diazenecarboxylate 

Downstream Products

• 55895-91-5 ethyl 2-amino-3-(4-nitrophenyl) propanoate 
• 27892-88-2 p-nitrocinnamonitrile 
• 27892-88-2 (E)-4-nitrocinnamonitrile 
• 61798-01-4 4-(3-aminopropyl)aniline 
• 18910-12-8 2-bromo-3-(4-nitro-phenyl)-propionic acid 
• 20797-42-6 2-chloro-3-(4-nitro-phenyl)-propionic acid 
• 57460-34-1 ethyl 2-chloro-3-(4-nitrophenyl)propionate 
• 18166-61-5 2-chloro-3-(4-nitro-phenyl)-propionic acid amide 

Relevant articles and documents

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4-substituted tert-butyl phenylazocarboxylates-synthetic equivalents for the para-phenyl radical cation

First electrophile, then radical: 4-Substituted tert-butyl phenylazocarboxylates 1 are versatile synthetic equivalents of the para-phenyl radical cation 2. The tert-butyloxycarbonylazo group enables nucleophilic substitutions to proceed under mild conditions and can later be employed for the generation of aryl radicals. Copyright

ARYL RADICALS BY COPPER(II) OXIDATION OF HYDRAZINES: A NEW METHOD FOR THE OXIDATIVE AND REDUCTIVE ARYLATION OF ALKENES

A new source of aryl radicals interesting from the preparative point of view has been found in the reaction of arylhydrazines and copper(II) sulfate.The process allows selectively both the reductive and oxidative arylation of alkenes.