17875-18-2

Basic information

• Product Name: 1-AMINO-3-BUTENE HYDROCHLORIDE
• Synonyms: 3-Butenylamine hydrochloride;3-BUTEN-1-AMINE HYDROCHLORIDE;4-Aminobut-1-ene hydrochloride;3-BUTEN-1-AMINE HCL;1-Amino-3-butene hydrochloride, 3-Buten-1-amine hydrochloride, 4-Amino-1-butene hydrochloride;but-3-en-1-aMine hydrochloride;3-ButenylaMine hydrochloride 97%;3-Butenamine hydrochloride
• CAS NO: 17875-18-2
• Molecular Formula: C₄H₁₀N*Cl
• Molecular Weight: 107.58
• Mol File: 17875-18-2.mol
• Article Data: 9

Chemical Properties

• Melting Point: 176-180 °C(lit.)
• Boiling Point: 82.5°C at 760 mmHg
• Appearance: /
• Vapor Pressure: 78.5mmHg at 25°C
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• CAS DataBase Reference: 1-AMINO-3-BUTENE HYDROCHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-AMINO-3-BUTENE HYDROCHLORIDE(17875-18-2)
• EPA Substance Registry System: 1-AMINO-3-BUTENE HYDROCHLORIDE(17875-18-2)

Safety Data

• Hazard Codes: T
• Statements: 25-37/38-41-42/43
• Safety Statements: 22-26-36/37/39-45
• RIDADR: UN 2811 6.1/PG 3
• WGK Germany: 3
• Hazardous Substances Data: 17875-18-2(Hazardous Substances Data)

Usage

Uses

3-Butenylamine hydrochloride can be used to synthesize 2-(3-butenylamino)-3-chloronaphthalene-1,4-dione via reaction with 2,3-dichloro-1,4-naphthoquinone in the presence of sodium bicarbonate.

InChI:InChI=1/C4H9N.ClH/c1-2-3-4-5;/h2H,1,3-5H2;1H

Upstream product

• 113738-20-8 4-azido-1-butene 
• 109-75-1 but-3-enenitrile 
• 627-27-0 homoalylic alcohol 
• 52898-32-5 N-(3-butenyl)phthalimide 
• 88211-46-5 1-buten-3 

Downstream Products

• 132547-64-9 N-(3-butenyl) benzyl carbamate 
• 1032392-72-5 (Z)-tert-butyl-1-(3-(4-(allyloxy)phenyl)-3-(ethoxyimino)-propanoylimino)-2-(4-(2-(but-3-enylamino)acetamido)-3,5-dichlorophenyl)ethyl-carbamate 
• 1100748-81-9 C₁₆H₂₂N₂ 
• 1391999-68-0 tert-butyl 2-(3-(but-3-en-1-ylcarbamoyl)-5-isopropoxyphenoxy)acetate 
• 1381808-11-2 ((S)-1-{(S)-2-((S)-3-but-3-enylcarbamoyl-tetrahydro-pyridazin-1-yl)-1-[3-(tert-butyl-dimethyl-silanyloxy)-benzyl]-2-oxo-ethyl carbamoyl}-2-methyl-propyl)-carbamic acid tert-butyl ester 
• 51411-39-3 N-(but-3-en-1-yl)-1,1-diphenylmethanimine 
• 1260369-66-1 methyl (R)-2-benzyl-3-(but-3-enylamino)-2-(2-nitrophenylsulfonamido)-propanoate 
• 90870-33-0 N-(2-nitrobenzenesulfonyl)-N-(but-3-enyl)amine 
• 1061262-00-7 N^ω-benzyloxycarbonyl-N^ω'-(but-3-enyl)-N^α-tert-butyloxycarbonyl-L-arginine tert-butyl ester 
• 847550-03-2 tert-butyl (S)-(1-(but-3-en-1-ylamino)-1-oxo-3-phenylpropan-2-yl)carbamate 
• 156731-40-7 tert-butyl N-but-3-enylcarbamate 
• 156025-94-4 N-(but-3-enyl)-2-(3-methoxyphenyl)acetamide 
• 10285-80-0 N-tosyl-3-butenylamine 
• 848678-22-8 [2-(7-benzyloxymethyl-1,5-dioxaspiro[5.5]undec-7-yl)ethyl]but-3-enylamine 

Relevant articles and documents

Dimethylamine adducts of allylic triorganoboranes as effective reagents for Petasis-type homoallylation of primary amines with formaldehyde

Dimethylamine adducts of triallyl-, triprenyl- and trans-cinnamyl(dipropyl)borane are effective reagents for mild homoallylation of primary amines with aqueous formaldehyde in MeOH without an inert atmosphere. A new concept is proposed for the explanation of the high stability of allylborane-amine adducts in aqueous MeOH.

Chiral 1,2-dialkenyl diaziridines: Synthesis, enantioselective separation, and nitrogen inversion barriers

Trans-1,2-Disubstituted diaziridines form stable enantiomers at ambient conditions because of the two stereogenic pyramidal nitrogen atoms. Functionalized trans-1,2-disubstituted diaziridines can be utilized as a chiral switching moiety between two enantiomeric states in more complex molecular structures. However, the synthesis of functionalized diaziridines is quite challenging, because of the limited tolerance of reaction conditions that can be applied. Here we present a strategy to make trans-1,2-disubstituted diaziridines accessible as versatile building blocks in C-C-bond formations, i.e., the Heck reaction, and therefore introducing aryl substituents. The synthesis of trans-1,2-dialkenyl diaziridines with terminal alkenyl substituents and their stereodynamic properties are described.

Synthesis of 3-oxoazacyclohept-4-enes by ring-closing metathesis. Application to the synthesis of an inhibitor of cathepsin K

The ring-closing metathesis allows the formation of 3-oxoazacyclohept-4-enes from but-3-enamine. By using this methodology, the synthesis of an inhibitor of cathepsin K was achieved in 10 steps from but-3-enamine.