17964-79-3

Upstream product

• 6233-20-1 trichloro(2-chloroethyl)silane 
• 108-88-3 toluene 
• 18077-07-1 (2,2-dichloroethyl)-trichlorosilane 
• 7446-70-0 aluminium trichloride 
• 622-97-9 1-ethenyl-4-methylbenzene 
• 92-84-2 10H-phenothiazine 
• 684-00-4 (1,2-dichloroethyl)-trichlorosilane 

Downstream Products

• 27490-76-2 trimethyl-(4-methyl-phenethyl)-silane 

Relevant academic research and scientific papers

Potassium Alkylpentafluorosilicates, Primary Alkyl Radical Precursors in the C-1 Alkylation of Tetrahydroisoquinolines

In this study, we demonstrate that potassium alkylpentafluorosilicates (RSiF5K2) are efficient primary alkyl radical precursors for selective C(sp3)-C(sp3) bond-forming reactions. RSiF5K2 reagents are white, free-flowing solids and are moisture and air stable. This class of reagents enables the direct C-1 alkylation of tetrahydroisoquinolines under mild conditions via single-electron transfer. The broad substrate scope of both alkylpentafluorosilicates and tetrahydroisoquinolines is tolerated in this transformation. Both radical scavenger and EPR capture experiments show that the primary radical is generated by the oxidation of RSiF5K2. A mechanism involving alkyl radical addition to an iminium salt followed by reduction by an amine is proposed.

ACTIVATED HALO-CONTAINING ARALKYLSILANE

The invention is directed to an activated halo-containing aralkylsilanes possessing at least one hydrolyzable group bonded to a silicon atom and at least one halo functional group bonded to a carbon atom to which both the silicon atom and an aromatic grou

ACTIVATED HALO-CONTAINING ARALKYLSILANE COMPOSITION, PROCESS OF PREPARING SAME AND RUBBER COMPOSITIONS MADE THEREFROM

The invention is directed to an activated halo-containing aralkylsilanes possessing at least one hydrolyzable group bonded to a silicon atom and at least one halo functional group bonded to a carbon atom to which both the silicon atom and an aromatic group are covalently bonded. The invention is also directed to a process for making such a silane as well as its use in rubber compositions and articles containing such rubber compositions, such as tires.

Trichlorosilyl groups containing organochlorosilanes and their preparation methods by the double-silylation of olefins with trichlorosilane

The present invention provides organosilicon compounds containing two trichlorosilyl groups and their preparation methods. Organosilicon compounds of formula II are prepared by reacting linear chain or cyclic olefins of formula I with trichlorosilane in the presence of quaternary organophosphonium salt as a catalyst.R1—HC=CH—R2??(I) 1In formulas I and II, R1 and R2 may be identical or different and represent a hydrogen atom, a linear or a cyclic C1-C8 alkyl, a linear or a cyclic C1-C8 alkenyl, benzyl, phenyl, a C1-C8 alkyl substituted phenyl group, two functional groups between R1 and R2 may be covalently bonded to form a C4-C8 ring with or without a carbon-carbon double bond.