18159-55-2 Usage
Description
TRI-T-BUTYLSILANE, also known as TTBS, is a chemical compound with the molecular formula C12H28Si. It is a colorless, flammable liquid with a strong characteristic odor. It is primarily used as a reducing agent in organic synthesis, a precursor for the introduction of silicon into organic molecules, a protective group for alcohols, and a reagent for the deprotection of silyl ethers. TRI-T-BUTYLSILANE is also employed in the production of silicon-based materials and as a component in the manufacture of electronic devices and other high-technology products. Due to its potentially hazardous nature, it requires careful handling and storage to minimize the risk of fire and environmental contamination.
Uses
Used in Organic Synthesis:
TRI-T-BUTYLSILANE is used as a reducing agent for various organic synthesis reactions, facilitating the conversion of functional groups and improving the efficiency of the synthesis process.
Used in Silicon Incorporation:
TRI-T-BUTYLSILANE is used as a precursor for the introduction of silicon into organic molecules, enabling the synthesis of organosilicon compounds with unique properties and applications.
Used in Protective Group Chemistry:
TRI-T-BUTYLSILANE is used as a protective group for alcohols, allowing selective reactions to occur at other functional groups while preventing unwanted side reactions at the alcohol moiety.
Used in Silyl Ether Deprotection:
TRI-T-BUTYLSILANE is used as a reagent for the deprotection of silyl ethers, enabling the selective removal of silyl protecting groups under mild conditions.
Used in Silicon-Based Material Production:
TRI-T-BUTYLSILANE is used in the production of silicon-based materials, such as ceramics, glasses, and polymers, due to its ability to incorporate silicon into various structures.
Used in Electronics and High-Technology Manufacturing:
TRI-T-BUTYLSILANE is used as a component in the manufacture of electronic devices and other high-technology products, such as semiconductors, solar cells, and sensors, owing to its role in creating silicon-based materials with specific electronic properties.
Used in Chemical Research:
TRI-T-BUTYLSILANE is used in chemical research for the development of new synthetic methods, the study of organosilicon compounds, and the exploration of its potential applications in various fields.
Check Digit Verification of cas no
The CAS Registry Mumber 18159-55-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,1,5 and 9 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 18159-55:
(7*1)+(6*8)+(5*1)+(4*5)+(3*9)+(2*5)+(1*5)=122
122 % 10 = 2
So 18159-55-2 is a valid CAS Registry Number.
InChI:InChI=1/C12H28Si/c1-10(2,3)13(11(4,5)6)12(7,8)9/h13H,1-9H3
18159-55-2Relevant articles and documents
Dexheimer,Spialter
, p. 1771 (1975)
Dexheimer et al.
, p. 21,26 (1975)
Isoelectronic caesium compounds: The triphosphenide Cs[tBu 3SiPPPSitBu3] and the enolate Cs[OCH=CH2]
Lerner, Hans-Wolfram,Saenger, Inge,Schoedel, Frauke,Lorbach, Andreas,Bolte, Michael,Wagner, Matthias
, p. 787 - 792 (2008/09/20)
The caesium triphosphenide Cs[tBu3SiPPPSitBu3] was accessible from the reaction of CsF with the sodium triphosphenide Na[tBu 3SiPPPSitBu3] in tetrahydrofuran at room temperature. In contrast to the preparation of tetrahydrofuran-solvated silanides M[SitBu 3] (M = Li, Na, K), our efforts to synthesize the caesium silanide Cs[SitBu3] as a tetrahydrofuran complex failed. When tBu 3SiBr was treated with an excess of caesium metal in tetrahydrofuran at room temperature, the caesium enolate Cs[OCH=CH2] and the supersilane tBu3SiH formed rather than the silanide Cs[SitBu 3]. X-Ray quality crystals of the enolate Cs[OCH=CH2] (orthorhombic, Pnma) were obtained from tetrahydrofuran at ambient temperature. In contrast to the structures of its homologues M[tBu3SiPPPSitBu 3] (M = Na, K), the caesium triphosphenide Cs[tBu 3SiPPPSitBu3] features a polymer in the solid state (orthorhombic, Cmcm). The Royal Society of Chemistry.
Tri-tert-butylsilyl(triisopropylsilyl)silylene (tBu)3Si-Si-Si(iPr)3 and chemical evidence for its reactions from a triplet electronic state [15]
Jiang,Gaspar
, p. 8622 - 8623 (2007/10/03)
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