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Silane, tris(1,1-dimethylethyl)-

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Name

Silane, tris(1,1-dimethylethyl)-

EINECS N/A
CAS No. 18159-55-2 Density N/A
PSA 0.00000 LogP 4.61380
Solubility N/A Melting Point 33-44°C
Formula C12H28Si Boiling Point 204.482 °C at 760 mmHg
Molecular Weight 200.44 Flash Point 78.868 °C
Transport Information N/A Appearance N/A
Safety 26-36/37/39 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 18159-55-2 (TRI-T-BUTYLSILANE) Hazard Symbols N/A
Synonyms

Tri-tert-butylhydrosilane;Silane,tri-tert-butyl- (6CI,8CI);Tris(tert-butyl)silane;Tri-tert-butylsilane;

Article Data 2

Silane, tris(1,1-dimethylethyl)- Specification

This chemical is called Silane, tris(1,1-dimethylethyl)-, and its systematic name is tri-tert-butylsilane. With the molecular formula of C12H28Si, its molecular weight is 200.44. The CAS registry number of this chemical is 18159-55-2.

Other characteristics of the Silane, tris(1,1-dimethylethyl)- can be summarised as followings: (1)ACD/LogP: 5.94; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 6; (4)ACD/LogD (pH 7.4): 6; (5)ACD/BCF (pH 5.5): 13838; (6)ACD/BCF (pH 7.4): 13838; (7)ACD/KOC (pH 5.5): 32045; (8)ACD/KOC (pH 7.4): 32045; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Flash Point: 78.868 °C; (13)Enthalpy of Vaporization: 42.271 kJ/mol; (14)Boiling Point: 204.482 °C at 760 mmHg; (15)Vapour Pressure: 0.376 mmHg at 25°C.

Production method of this chemical: The Silane, tris(1,1-dimethylethyl)- could be obtained by the reactant of tert-butyl-lithium. This reaction needs the reagent of SiF4, and the solvent of pentane. The yield is 95 %.

Uses of this chemical: The Silane, tris(1,1-dimethylethyl)- could react with trifluoro-methanesulfonic acid, and obtain the Trifluormethansulfonsaeure-tri-tert-butylsilylester. This reaction needs the solvent of heptane. The yield is 68 %. In addition, this reaction should be taken at the temperature of -78-20 °C.

When you are using this chemical, please be cautious about it as the following: This chemical is irritating to eyes, respiratory system and skin. You should wear suitable protective clothing if you use it. In case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure: 
1.SMILES: CC(C)(C)[SiH](C(C)(C)C)C(C)(C)C
2.InChI: InChI=1/C12H28Si/c1-10(2,3)13(11(4,5)6)12(7,8)9/h13H,1-9H3
3.InChIKey: DKBGMFLYIUKQKE-UHFFFAOYAB

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