18173-74-5Relevant articles and documents
Highly conductive trimethylsilyl oligo(ethylene oxide) electrolytes for energy storage applications
Zhang, Lingzhi,Zhang, Zhengcheng,Harring, Scott,Straughan, Megan,Butorac, Rachel,Chen, Zonghai,Lyons, Leslie,Amine, Khalil,West, Robert
, p. 3713 - 3717 (2008)
Monomethyl ethers of oligoethylene glycols with different chain lengths were converted to trimethylsilyl derivatives by reacting with trimethylchlorosilane in the presence of triethylamine, or by directly refluxing with excess trimethylchlorosilane or hex
Glycosyl Fluorides as Intermediates in BF3·OEt2-Promoted Glycosylation with Trichloroacetimidates
Nielsen, Michael M.,Stougaard, Bolette A.,Bols, Mikael,Glibstrup, Emil,Pedersen, Christian M.
supporting information, p. 1281 - 1284 (2017/03/17)
Glycosyl fluorides have been found to be important intermediates in glycosylations with trichloroacetimidate donors and BF3·OEt2 activation (0.2–1 equiv.). Low-temperature NMR spectroscopy experiments revealed that the α-trichloroacetimidate was transformed into the glycosyl fluoride with inversion of stereochemistry, whereas the β anomer was not. A concerted mechanism was suggested for the stereospecific formation of glycosyl fluorides, which is not accounted for in the classic mechanism.
Silicon-29 NMR spectra of trimethylsilylated alcohols
Kvicalova, Magdalena,Cermak, Jan,Blechta, Vratislav,Schraml, Jan
, p. 816 - 820 (2007/10/03)
29Si NMR spectra of trimethylsilyl (TMS) derivatives of 26 simple alcohols were measured under standardized conditions (i.e., in sufficiently diluted deuteriochloroform solutions). Due to association with the solvent the chemical shifts are in almost all cases larger than those reported earlier for different solutions. This observation is in agreement with the proposed mechanism of steric effects as being due to sterically controlled association with the solvent. The use of chloroform as a solvent enhances steric effects hut at the same time it can reduce small differences due to polar effects in closely related compounds. In the studied class of compounds the gross dependence of the chemical shift on polar effects is not substantially affected by the change of the solvent.