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N,N'-bis(trimethylsilyl)ethylenediamine is a chemical compound with the molecular formula C8H24N2Si2. It is a colorless, clear liquid that is commonly used as a reagent in organic synthesis and as a ligand in metal-catalyzed reactions. Characterized by the presence of two trimethylsilyl groups attached to the nitrogen atoms of the ethylenediamine backbone, these silyl groups provide protection to the nitrogen atoms and prevent unwanted side reactions. This makes N,N'-bis(trimethylsilyl)ethylenediamine a versatile and valuable tool in chemical research and industry. Additionally, it is known for its ability to form stable complexes with transition metals, contributing to its utility in various catalytic processes.

1821-99-4

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1821-99-4 Usage

Uses

Used in Organic Synthesis:
N,N'-bis(trimethylsilyl)ethylenediamine is used as a reagent for its ability to protect nitrogen atoms in organic synthesis, preventing unwanted side reactions and facilitating the formation of desired products.
Used in Metal-Catalyzed Reactions:
In the field of catalysis, N,N'-bis(trimethylsilyl)ethylenediamine is used as a ligand to form stable complexes with transition metals, enhancing the efficiency and selectivity of various catalytic processes.
Used in Chemical Research:
N,N'-bis(trimethylsilyl)ethylenediamine is utilized as a research tool to explore new reaction pathways and develop innovative synthetic methods, thanks to its unique structural features and protective capabilities for nitrogen atoms.
Used in Industrial Applications:
In the chemical industry, N,N'-bis(trimethylsilyl)ethylenediamine is employed to improve the synthesis of complex organic molecules and fine chemicals, leveraging its protective and catalytic properties to streamline production processes and increase yields.

Check Digit Verification of cas no

The CAS Registry Mumber 1821-99-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,8,2 and 1 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1821-99:
(6*1)+(5*8)+(4*2)+(3*1)+(2*9)+(1*9)=84
84 % 10 = 4
So 1821-99-4 is a valid CAS Registry Number.

1821-99-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name N,N'-bis(trimethylsilyl)ethylenediamine

1.2 Other means of identification

Product number -
Other names 1,3-bis(trimethylsylil)ethylenediamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1821-99-4 SDS

1821-99-4Relevant academic research and scientific papers

Thermal decomposition of [Me3SiNCH2CH2NSiMe3] · Li2(THF)2 to [LiN(SiMe3)2 · THF]2 via a 1,4-trimethylsilyl shift

Mack, Helmut,Frenzen, Gerlinde,Bendikov, Michael,Eisen, Moris S.

, p. 39 - 43 (1997)

The dilithium salt [Me3SiNCH2CH2NSiMe3] · Li2(THF)2 decomposes slowly upon heating forming a metastable structure of the crystalline [LiN(SiMe3) · THF]2. The crystal s

New cyclic and spirocyclic aminosilanes

B?hme, Uwe,Günther, Betty,Gerlach, Daniela,Gevorgyan, Lia,Herbig, Marcus,Kroke, Edwin,Scholz, Henrik,Schwarzer, Sandra,Wagler, J?rg

, p. 51 - 72 (2021/05/19)

New cyclic and spirocyclic aminosilanes were synthesised using ethylenediamine, 2-aminoben-zylamine, 1,8-diaminonaphthalene, o-phenylenediamine, and trans-cyclohexane-1,2-diamine as starting material. These diamines were converted into aminosilanes using

Binuclear tantalum complex and preparation method thereof

-

Paragraph 0026; 0029, (2020/07/13)

The invention relates to a binuclear tantalum complex and a preparation method thereof. The preparation method comprises the steps of: 1) dissolving a diamino compound into an alkane solvent, dropwiseadding trimethylchlorosilane, carrying out stirring, th

Intramolecular catalysis of aminolysis of phosphorus heterocycles incorporating an α-aminoamide moiety. III. Synthesis of 2-oxo or 2-thioxo 1,3-disulfonyl-1,3,2-diazaphospholidines and reactions with amines and alcohols

Dujols,Mulliez

, p. 475 - 480 (2007/10/03)

A series of 2-oxo or 2-thioxo 1,3-disulfonyl-1,3,2-diazaphospholidines 4 was prepared by condensation of phosphonyl dichlorides 2 with bis-N,N′-sulfonylethylenediamines 1 in pyridine. Complete aminolysis or alcoholysis of heterocycles 4 took place with regeneration of sulfonyldiamines 1. These reactions are very sensitive to steric hindrance, and hydrolysis is generally favoured over aminolysis. The results are discussed in terms of mechanisms of phosphorylation.

Silaheterocycles, XVII. Synthesis and Cycloaddition Reactions of Novel Amino Cyclic Silenes

Auner, Norbert,Penzenstadler, Erika

, p. 795 - 804 (2007/10/02)

The silene 2 is formed by reacting 2-chloro-1,3-bis(trimethylsilyl)-2-vinyl-1,3-diaza-2-silacyclopentane (5) with LiBut in n-pentane in the temperature range from -10 to + 10 deg C.The reaction primarily leads to the corresponding α-lithio addu

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