1821-99-4Relevant academic research and scientific papers
Thermal decomposition of [Me3SiNCH2CH2NSiMe3] · Li2(THF)2 to [LiN(SiMe3)2 · THF]2 via a 1,4-trimethylsilyl shift
Mack, Helmut,Frenzen, Gerlinde,Bendikov, Michael,Eisen, Moris S.
, p. 39 - 43 (1997)
The dilithium salt [Me3SiNCH2CH2NSiMe3] · Li2(THF)2 decomposes slowly upon heating forming a metastable structure of the crystalline [LiN(SiMe3) · THF]2. The crystal s
New cyclic and spirocyclic aminosilanes
B?hme, Uwe,Günther, Betty,Gerlach, Daniela,Gevorgyan, Lia,Herbig, Marcus,Kroke, Edwin,Scholz, Henrik,Schwarzer, Sandra,Wagler, J?rg
, p. 51 - 72 (2021/05/19)
New cyclic and spirocyclic aminosilanes were synthesised using ethylenediamine, 2-aminoben-zylamine, 1,8-diaminonaphthalene, o-phenylenediamine, and trans-cyclohexane-1,2-diamine as starting material. These diamines were converted into aminosilanes using
Binuclear tantalum complex and preparation method thereof
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Paragraph 0026; 0029, (2020/07/13)
The invention relates to a binuclear tantalum complex and a preparation method thereof. The preparation method comprises the steps of: 1) dissolving a diamino compound into an alkane solvent, dropwiseadding trimethylchlorosilane, carrying out stirring, th
Intramolecular catalysis of aminolysis of phosphorus heterocycles incorporating an α-aminoamide moiety. III. Synthesis of 2-oxo or 2-thioxo 1,3-disulfonyl-1,3,2-diazaphospholidines and reactions with amines and alcohols
Dujols,Mulliez
, p. 475 - 480 (2007/10/03)
A series of 2-oxo or 2-thioxo 1,3-disulfonyl-1,3,2-diazaphospholidines 4 was prepared by condensation of phosphonyl dichlorides 2 with bis-N,N′-sulfonylethylenediamines 1 in pyridine. Complete aminolysis or alcoholysis of heterocycles 4 took place with regeneration of sulfonyldiamines 1. These reactions are very sensitive to steric hindrance, and hydrolysis is generally favoured over aminolysis. The results are discussed in terms of mechanisms of phosphorylation.
Silaheterocycles, XVII. Synthesis and Cycloaddition Reactions of Novel Amino Cyclic Silenes
Auner, Norbert,Penzenstadler, Erika
, p. 795 - 804 (2007/10/02)
The silene 2 is formed by reacting 2-chloro-1,3-bis(trimethylsilyl)-2-vinyl-1,3-diaza-2-silacyclopentane (5) with LiBut in n-pentane in the temperature range from -10 to + 10 deg C.The reaction primarily leads to the corresponding α-lithio addu
