183-84-6

Basic information

• Product Name: Dicyclohexanone Diperoxide
• Synonyms: 7,8,15,16-Tetraoxadispiro[5.2.5.2]hexadecane;Dicyclohexanone Diperoxide;Dispiro[cyclohexane-1,3'-[1,2,4,5]tetroxane-6',1''-cyclohexane];Bis[cyclohexylidene]peroxide;Cyclohexanone peroxide cyclic dimer;Cyclohexanone peroxide dimer;Dicyclohexylidene diperoxide;Dimeric cyclohexanone peroxide
• CAS NO: 183-84-6
• Molecular Formula: C₁₂H₂₀O₄
• Molecular Weight: 228.2848
• Mol File: 183-84-6.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 291.8°Cat760mmHg
• Flash Point: 113.4°C
• Appearance: /
• Density: 1.16g/cm³
• Vapor Pressure: 0.00333mmHg at 25°C
• Refractive Index: 1.507
• CAS DataBase Reference: Dicyclohexanone Diperoxide(CAS DataBase Reference)
• NIST Chemistry Reference: Dicyclohexanone Diperoxide(183-84-6)
• EPA Substance Registry System: Dicyclohexanone Diperoxide(183-84-6)

Safety Data

• Hazardous Substances Data: 183-84-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H20O4/c1-3-7-11(8-4-1)13-15-12(16-14-11)9-5-2-6-10-12/h1-10H2

Upstream product

• 882-59-7 1,1-diphenyloxirane 
• 2407-94-5 1,1'-dihydroxycyclohexyl peroxide 
• 23888-15-5 3,5-diphenyl-1,2,4-trioxacyclopentane 
• 4233-18-5 bicyclohexylidene 
• 10028-15-6 ozone 
• 108-94-1 cyclohexanone 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 2699-11-8 1,1-dihydroperoxycyclohexane 
• 4316-35-2 acetophenone dimethyl acetal 
• 1112-78-3 2,2-dimethoxy-4-methylpentane 
• 67-56-1 methanol 
• 286-20-4 cyclohexane-1,2-epoxide 
• 19096-89-0 methoxymethylenecyclohexane 
• 87943-83-7 1-Phenyl-9,10,11-trioxa-tricyclo[6.2.1.0^2,7]undeca-2,4,6-triene 

Downstream Products

• 502-44-3 hexahydro-2H-oxepin-2-one 
• 1725-03-7 oxacyclododecan-2-one 
• 293-96-9 cyclodecane 
• 108-94-1 cyclohexanone 
• 1191-25-9 6-Hydroxyhexanoic acid 
• 108-93-0 cyclohexanol 

Relevant articles and documents

New preparation of 1,2,4,5-tetraoxanes

A convenient procedure was developed for the synthesis of 1,2,4,5-tetraoxanes based on the reaction of gem-bishydroper-oxycycloalkanes with ketals and acetals catalyzed by boron trifluoride etherate, which makes it possible to prepare the target products

METHOD FOR MANUFACTURING ESTER

The present invention relates to a method for manufacturing an ester from a ketone or an aldehyde, which is a reactive substrate, by a Baeyer-Villiger oxidation reaction using hydrogen peroxide, and in this method, as a catalyst, M(BAr4)n, which is a metal borate, is used (M represents an alkali metal or an alkaline earth metal; Ar represents an aryl; and n is the same number as the valence of M). For example, when cyclohexanone was used as the reactive substrate, and Sr[B(3,5-CF3C6H3)4]2 was used as the catalyst, ε-caprolactone was obtained at an isolated yield of 82%.

Supported sulfonic acid as green and efficient catalyst for Baeyer-Villiger oxidation with 30% aqueous hydrogen peroxide

Silica-supported propylsulfonic acid is a very good heterogeneous catalyst for the Baeyer-Villiger oxidation of cyclic ketones to lactones with stoichiometric 30% aqueous hydrogen peroxide in 1,1,1,3,3,3-hexafluoro-2- propanol as solvent.