18427-47-9

Basic information

• Product Name: Cyclohexanone, 2,6-dibromo-5-methyl-2-(1-methylethyl)-
• CAS NO: 18427-47-9
• Molecular Formula: C10H16Br2O
• Molecular Weight: 312.044
• Mol File: 18427-47-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2,6-dibromo-5-methyl-2-(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2,6-dibromo-5-methyl-2-(1-methylethyl)-(18427-47-9)
• EPA Substance Registry System: Cyclohexanone, 2,6-dibromo-5-methyl-2-(1-methylethyl)-(18427-47-9)

Safety Data

• Hazardous Substances Data: 18427-47-9(Hazardous Substances Data)

Upstream product

• 10458-14-7 Menthone 
• 67-66-3 chloroform 
• 7726-95-6 bromine 
• 10458-14-7 (2R,5S)-menthone 
• 55985-69-8 4-bromo-p-menthan-3-one 
• 1196-31-2 (1R,4R)-(+)-isomenthone 

Downstream Products

• 89-83-8 thymol 
• 54783-36-7 ξ-diosphenol 
• 30313-90-7 4,4',4''-trithymylmethane 
• 84817-96-9 tris-(4-acetoxy-5-isopropyl-2-methyl-phenyl)-methane 
• 490-03-9 2-hydroxy-1-p-menthen-3-one 
• 60507-82-6 (6R)-(+)-Ψ-diosphenol 
• 468722-73-8 (6S)-(-)-Ψ-diosphenol 

Relevant articles and documents

Stereoselective synthesis of (6R)- and (6S)-diosphenol and Ψ-diosphenol

Methods are discussed for the stereoselective synthesis of the (R)-and (S)-enantiomers of the diosphenols (5)-(8) by utilizing the commercially available stereoisomers (9), (12), (23) and (25) of carvone and limonene, respectively, as chiral starting materials.

CONVENIENT PREPARATION OF 1,2-CYCLOHEXANEDIONES

1,2-Cyclohexanedione and 3-alkyl-1,2-cyclohexanediones were prepared in good to excellent yields from the corresponding 2,6-dibromocyclohexanones by treatment with aqueous NaOH.