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Methyl 5-(4-methoxyphenyl)-5-oxopentanoate, also known as methyl 5-(p-anisoyl)-5-oxopentanoate, is a chemical compound characterized by its molecular formula C13H16O4. It presents as a white to off-white crystalline powder with a molecular weight of 236.26 g/mol. Methyl 5-(4-methoxyphenyl)-5-oxopentanoate is recognized for its role as an intermediate in the synthesis of pharmaceuticals and organic compounds, as well as for its potential biological activities, including anti-inflammatory and anti-cancer properties. Methyl 5-(4-methoxyphenyl)-5-oxopentanoate is a valuable component in research and development within the pharmaceutical and chemical industries.

1847-68-3

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1847-68-3 Usage

Uses

Used in Pharmaceutical Industry:
Methyl 5-(4-methoxyphenyl)-5-oxopentanoate is used as a key intermediate in the synthesis of various pharmaceuticals for its ability to contribute to the development of new drugs and improve existing ones.
Used in Organic Compounds Synthesis:
In the chemical industry, Methyl 5-(4-methoxyphenyl)-5-oxopentanoate is utilized as an intermediate in the synthesis of organic compounds, playing a crucial role in creating a range of chemical products.
Used in Research and Development:
Methyl 5-(4-methoxyphenyl)-5-oxopentanoate is employed as a research compound for exploring its anti-inflammatory and anti-cancer properties, which can lead to advancements in medical treatments and therapies.
Used in Drug Development:
Due to its potential biological activities, Methyl 5-(4-methoxyphenyl)-5-oxopentanoate is used in drug development to create new pharmaceuticals that can target inflammation and cancer, offering novel treatment options for patients.

Check Digit Verification of cas no

The CAS Registry Mumber 1847-68-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,8,4 and 7 respectively; the second part has 2 digits, 6 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1847-68:
(6*1)+(5*8)+(4*4)+(3*7)+(2*6)+(1*8)=103
103 % 10 = 3
So 1847-68-3 is a valid CAS Registry Number.

1847-68-3Relevant academic research and scientific papers

Combined Photoredox/Enzymatic C?H Benzylic Hydroxylations

Betori, Rick C.,May, Catherine M.,Scheidt, Karl A.

, p. 16490 - 16494 (2019/11/03)

Chemical transformations that install heteroatoms into C?H bonds are of significant interest because they streamline the construction of value-added small molecules. Direct C?H oxyfunctionalization, or the one step conversion of a C?H bond to a C?O bond, could be a highly enabling transformation due to the prevalence of the resulting enantioenriched alcohols in pharmaceuticals and natural products,. Here we report a single-flask photoredox/enzymatic process for direct C?H hydroxylation that proceeds with broad reactivity, chemoselectivity and enantioselectivity. This unified strategy advances general photoredox and enzymatic catalysis synergy and enables chemoenzymatic processes for powerful and selective oxidative transformations.

Manganese-catalyzed ring-opening carbonylation of cyclobutanol derivatives

Meyer, Tim,Yin, Zhiping,Wu, Xiao-Feng

supporting information, p. 864 - 867 (2019/02/20)

Herein, we report a manganese-catalyzed ring-opening carbonylation of cyclobutanol derivatives through cyclic C–C bond cleavage. The reaction happens via a radical-mediated pathway to selectively generate 1,5-ketoesters. A variety of substrates with subst

Asymmetric iodolactonization utilizing chiral squaramides

Tungen, Jorn E.,Nolsoe, Jens M. J.,Hansen, Trond V.

supporting information, p. 5884 - 5887 (2013/02/23)

Asymmetric iodolactonization of γ- and δ-unsaturated carboxylic acids has been explored in the presence of six different chiral organocatalysts 5-8. The catalyst 6b was found to facilitate the cyclization of 5-arylhex-5-enoic acids 1 to the corresponding

Gold-catalysed cyclic ether formation from diols

Jiang, Xiaolu,London, Emma K.,Morris, David J.,Clarkson, Guy J.,Wills, Martin

supporting information; experimental part, p. 9828 - 9834 (2011/02/23)

Gold(I) and (III) salts have been found to be highly effective at the catalysis of ether formation from alcohols. Intramolecular ether formation of a 1,5-diol was also achieved, with a stereoselectivity that indicates that an SN1 mechanism predominates. In an attempt to form a seven-membered ring, a stable 14-membered dimer product was also formed. Attempts to control the diastereoselectivity of the reaction using a chiral anionic counterion did not give products with a high de.

Increasing the open circuit voltage of bulk-heterojunction solar cells by raising the LUMO level of the acceptor

Kooistra, Floris B.,Knol, Joop,Kastenberg, Fredrik,Popescu, Lacramioara M.,Verhees, Wiljan J. H.,Kroon, Jan M.,Hummelen, Jan C.

, p. 551 - 554 (2007/10/03)

We report the synthesis, characterization, and electrochemical properties of ten new fullerene derivatives for usage in organic solar cells. The phenyl ring of PCBM was substituted with electron-donating and electron-withdrawing substituents to study thei

A general and straightforward approach to α,ω-ketoesters

Babudri, Francesco,Fiandanese, Vito,Marchese, Giuseppe,Punzi, Angela

, p. 13513 - 13520 (2007/10/03)

Chemoselective cross-coupling reactions of monoesters of dicarboxylic acid chlorides with organocopper reagents derived from Grignard reagents, cuprous bromide, and lithium bromide, provide a simple and straightforward method for synthesizing a variety of ketoesters.

Aspects of Tautomerism. Part 15. Investigations on Oxo-participation in δ-Oxocarboxylic Acid Chlorides during their Formation and Alcoholysis

Shashidhar, M. Srikantaiah,Bhatt, M. Vivekananda

, p. 355 - 358 (2007/10/02)

Oxalyl chloride converts ring-substituted 4-benzoylbutyric acids into a mixture of normal and pseudoacid chlorides by two independent and competing pathways.Pseudoacid chlorides are formed by a concerted 2?+2?+2? pathway.I

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