1873-25-2Relevant articles and documents
Addy,Parker
, p. 644,648 (1965)
Conversion of epoxides to β-chlorohydrins with thionyl chloride and β-cyclodextrin in water
Surendra,Srilakshmi Krishnaveni,Nageswar,Rama Rao
, p. 2195 - 2201 (2007/10/03)
Several epoxides are efficiently converted to the corresponding β-chlorohydrins in impressive yields with thionyl chloride in the presence of β-cyclodextrin using water as solvent at room temperature. Copyright Taylor & Francis, Inc.
Demonstration of a phosphazirconocene as a catalyst for the ring opening of epoxides with TMSCI
Wang, Li-Sheng,Hollis, T. Keith
, p. 2543 - 2545 (2007/10/03)
(Matrix presented) In this study, it was demonstrated for the first time that a phosphazirconocene catalyzes the ring opening of epoxides with TMSCI. This reactivity leads to a facile preparation of chlorohydrins. The late transition metal Fe analogue was found to catalyze the reaction at rates and stereoselectivity comparable to those of the Zr complex.