1873-89-8Relevant articles and documents
1,1,1,5,5,5-HEXAMETHYLTRISILOXANE: PREPARATION AND SOME REACTIONS
Seyferth, Dietmar,Prud'homme, Christian C.,Wang, Wei-Liang
, p. 203 - 210 (1984)
1,1,1,5,5,5-Hexamethyltrisiloxane (I) was prepared by reaction of (Me3SiO)2Mg or of Me3SiOH with dichlorosilane.Its selective chlorination to give mostly Me3SiOSiHClOSiMe3 and only a small amount of Me3SiOSiCl2OSiMe3 was effected by its PdCl2-catalyzed reaction with CCl4.Photolysis of compound I gave H(Me3SiO)2SiSi(OSiMe3)2H in 30percent yield, as well as polymer.
Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: Synthesis of siloxanols
Arzumanyan, Ashot V.,Goncharova, Irina K.,Novikov, Roman A.,Milenin, Sergey A.,Boldyrev, Konstantin L.,Solyev, Pavel N.,Tkachev, Yaroslav V.,Volodin, Alexander D.,Smol'Yakov, Alexander F.,Korlyukov, Alexander A.,Muzafarov, Aziz M.
supporting information, p. 1467 - 1471 (2018/04/12)
A highly efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc)2 or Cu(OAc)2/NHPI-catalyzed oxidation of hydride siloxanes using "green", commercially available, simple inexpensive reagents and mild reaction conditions has been proposed. This is a general reaction for the synthesis of mono-, oligo- and polymeric siloxanols with various structures (linear, branched and cyclic).
Untersuchungen zu Substituenteneffekten in Tris(methylorganophenylsiloxy)silanen (RMePhSiO)3SiH
Popowski, Eckhard,Kraft, Oliver,Kelling, Hans,Jancke, Harald
, p. 30 - 31 (2007/10/02)
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