
Synthetic Communications p. 3895 - 3907 (1997)
Update date:2022-08-03
Topics: Deprotonation Nucleophilic substitution Nitrile Oxidative Addition Cyclic Voltammetry (CV) Substrate Electrochemical Cell Electrolyte Anode Cathode Mechanistic study Silyl group Radical intermediate electrode potential redox reaction Electrosynthesis Controlled Potential Electrolysis Faradaic Efficiency Current Density
Constantieux
Picard
Sacrificial anode technique has been used to synthetize title compounds in two different ways. First, use was made of α-chloronitriles as the starting materials, zinc as the anode and a THF-HMPA mixture as the solvent. Second, use of an aluminium-made anode, the nitrile being at the same time the substrate and the solvent was shown to be also efficient.
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Doi:10.1248/cpb.45.291
(1997)Doi:10.1016/S0040-4020(97)00083-5
(1997)Doi:10.1016/S0040-4039(98)00989-7
(1998)Doi:10.1016/S0040-4039(97)00475-9
(1997)Doi:10.1021/om961066z
(1997)Doi:10.1016/j.molcata.2013.01.016
(2013)