1913-85-5Relevant academic research and scientific papers
Reaction of Bistrifluoromethylaminosulphenyl Chloride with Fluoro-olefins and Hexafluorobut-2-yne under Free-radical Conditions
Service, Colin F.,Tipping, Anthony E.
, p. 135 - 140 (2007/10/02)
Reaction of bistrifluoromethylaminosulphenyl chloride with unsymmetrical fluoro-olefins in daylight or under photochemical conditions gives both possible 1:1 adducts (ca. 1:1) arising from homolytic fission of the S-Cl bond.Addition to octafluorobut-2-ene and hexafluorobut-2-yne gives mixtures of the syn- and anti- adducts.
Reaction of Bistrifluoromethylaminosulphenyl Chloride with Hydrocarbon Olefins and the Synthesis of Bistrifluoromethylaminosulphenylarenes
Service, Colin F.,Tipping, Anthony E.
, p. 91 - 96 (2007/10/02)
Reaction of bistrifluoromethylaminosulphenyl chloride with acyclic and alicyclic hydrocarbon olefins at -78 deg C in the dark affords 1:1 adducts of type in high yield.Treatment of diaryl disulphides with the N-bromo-amine (CF3)2NBr or of benzenesulphenyl chloride with the mercurial 2Hg provide convenient routes to bistrifluoromethylaminosulphenylarenes.
