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1915-96-4

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1915-96-4 Usage

General Description

D-2,3-Diaminopropionic acid, also known as beta, gamma-diaminopropionic acid, is a naturally occurring non-proteinogenic amino acid. It has a molecular structure consisting of two amine groups and a carboxylic acid group attached to a three-carbon chain. This chemical is found in certain plant and bacterial sources and has been identified as a component of some neurotoxic proteins. D-2,3-Diaminopropionic acid has been studied for its potential applications in drug discovery and development, as well as its role in the synthesis of bioactive compounds due to its unique chemical structure. It is also of interest in research related to the function and metabolism of amino acids in living organisms.

Check Digit Verification of cas no

The CAS Registry Mumber 1915-96-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,9,1 and 5 respectively; the second part has 2 digits, 9 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1915-96:
(6*1)+(5*9)+(4*1)+(3*5)+(2*9)+(1*6)=94
94 % 10 = 4
So 1915-96-4 is a valid CAS Registry Number.
InChI:InChI=1/C3H8N2O2/c4-1-2(5)3(6)7/h2H,1,4-5H2,(H,6,7)

1915-96-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name (2R)-2,3-diaminopropanoic acid

1.2 Other means of identification

Product number -
Other names 3-Amino-D-Alanine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1915-96-4 SDS

1915-96-4Relevant articles and documents

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Bickel

, p. 328 (1948)

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Synthesis of L-2,3-diaminopropionic acid, a siderophore and antibiotic precursor

Kobylarz, Marek J.,Grigg, Jason C.,Takayama, Shin-Ichi J.,Rai, Dushyant K.,Heinrichs, David E.,Murphy, Michael E.P.

, p. 379 - 388 (2014)

L-2,3-diaminopropionic acid (L-Dap) is an amino acid that is a precursor of antibiotics and staphyloferrin B a siderophore produced by Staphylococcus aureus. SbnA and SbnB are encoded by the staphyloferrin B biosynthetic gene cluster and are implicated in L-Dap biosynthesis. We demonstrate here that SbnA uses PLP and substrates O-phospho-L-serine and L-glutamate to produce a metabolite N-(1-amino-1-carboxyl-2-ethyl)-glutamic acid (ACEGA). SbnB is shown to use NAD+ to oxidatively hydrolyze ACEGA to yield α-ketoglutarate and L-Dap. Also, we describe crystal structures of SbnB in complex with NADH and ACEGA as well as with NAD+ and α-ketoglutarate to reveal the residues required for substrate binding, oxidation, and hydrolysis. SbnA and SbnB contribute to the iron sparing response of S. aureus that enables staphyloferrin B biosynthesis in the absence of an active tricarboxylic acid cycle.

Synthesis of the pyrimidine moiety of bleomycin

Umezawa,Morishima,Saito,et al.

, p. 6630 - 6631 (1980)

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Structures and Biosynthetic Pathway of Coprisamides C and D, 2-Alkenylcinnamic Acid-Containing Peptides from the Gut Bacterium of the Carrion Beetle Silpha perforata

Shin, Yern-Hyerk,Ban, Yeon Hee,Kim, Tae Ho,Bae, Eun Seo,Shin, Jongheon,Lee, Sang Kook,Jang, Jichan,Yoon, Yeo Joon,Oh, Dong-Chan

, (2021/02/26)

Coprisamides C and D (1 and 2) were isolated from a gut bacterium, Micromonospora sp. UTJ3, of the carrion beetle Silpha perforata. Based on the combined analysis of UV, MS, and NMR spectral data, the planar structures of 1 and 2 were elucidated to be unreported derivatives of coprisamides A and B, cyclic depsipeptides bearing a 2-alkenylcinnamic acid unit and the unusual amino acids β-methylaspartic acid and 2,3-diaminopropanoic acid. The absolute configuration of 1 was determined using the advanced Marfey's method, phenylglycine methyl ester derivatization, and J-based configuration analysis. The biosynthetic gene clusters for the coprisamides were investigated based on genomic data from coprisamide-producing strains Micromonospora sp. UTJ3 and Streptomyces sp. SNU533. Coprisamide C (1) was active against the Mycobacterium tuberculosis mc26230 strain.

Catalyst functional group cooperativity in the amino acid-catalysed nitroaldol condensation reaction

Karadeniz, Leman,Astley, Stephen T.

, p. 3407 - 3415 (2013/09/23)

Several amino acids and their derivatives have been evaluated as organic catalysts for the nitroaldol reaction. It was found that when an unprotected amino group and an unprotected carboxylate group were present in the organocatalyst, both the nitroaldol reaction and subsequent elimination could occur to afford nitroalkenes from aromatic aldehydes and nitromethane. The best results were obtained by use of γ-amino acids derived from l-glutamine. It is suggested that the amino group is important for intermediate Schiff base formation and that the free carboxylate group facilitates the elimination step.

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