Organic Synthesis with Sulfones n0XXIX Stereospecific hydrogenolysis of vinylic sulfones with grignards and transition metal catalysts (1).

DOI: 10.1016/S0040-4039(00)88328-8

Source and publish data:

Tetrahedron Letters p. 4311 - 4314 (1983)

Update date:2022-08-16

Topics:

Authors:

Fabre, J.-L.

Julia, M.

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Article abstract of DOI:10.1016/S0040-4039(00)88328-8

Hydrogenolysis of various vinylic sulfones to the corresponding olefins can be carried out by alkyl Grignard reagents with nickel or palladium catalysts.Yields are good to excellent.Retention of configuration is observed.The influence of ligands is discussed.

Full text of DOI:10.1016/S0040-4039(00)88328-8

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