1919-46-6

Basic information

• Product Name: 2,4,6-tris(3-methylphenoxy)-1,3,5-triazine
• Synonyms: 2,4,6-Tris(3-methylphenoxy)-1,3,5-triazine; 2,4,6-TRIS(M-TOLYLOXY)-S-TRIAZINE; s-Triazine, 2,4,6-tris(3-methylphenoxy)-
• CAS NO: 1919-46-6
• Molecular Formula: C₂₄H₂₁N₃O₃
• Molecular Weight: 399.4418
• Mol File: 1919-46-6.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 579.7°C at 760 mmHg
• Flash Point: 201.9°C
• Density: 1.211g/cm³
• Vapor Pressure: 7.88E-13mmHg at 25°C
• Refractive Index: 1.61
• CAS DataBase Reference: 2,4,6-tris(3-methylphenoxy)-1,3,5-triazine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-tris(3-methylphenoxy)-1,3,5-triazine(1919-46-6)
• EPA Substance Registry System: 2,4,6-tris(3-methylphenoxy)-1,3,5-triazine(1919-46-6)

Safety Data

• Hazardous Substances Data: 1919-46-6(Hazardous Substances Data)

Upstream product

• 108-77-0 1,3,5-trichloro-2,4,6-triazine 
• 3019-89-4 sodium 3-methylphenoxide 
• 36294-16-3 potassium m-methylphenoxide 
• 108-39-4 3-methyl-phenol 

Downstream Products

• 108-88-3 toluene 
• 23099-05-0 3-methyl-N-phenylbenzamide 
• 41882-53-5 N-benzyl-3-methylbenzamide 
• 53205-66-6 N‐cyclohexyl‐3‐methylbenzamide 
• 620-22-4 3-Methylbenzonitrile 

Relevant articles and documents

Nickel-catalyzed reductive amidation of aryl-triazine ethers

The reaction of activated phenolic compounds, 2,4,6-triaryloxy-1,3,5-triazine (aryl-triazine ethers), with various isocyanates or carbodiimides in the presence of a nickel pre-catalyst resulted in the synthesis of aryl amides in good to excellent yields.

Nickel-catalysed C–O bond reduction of 2,4,6-triaryloxy-1,3,5-triazines in 2-methyltetrahydrofuran

A nickel-catalysed reduction of phenol derivatives activated by 2,4,6-trichloro-1,3,5-triazine (TCT) in ecofriendly 2-methyltetrahydrofuran (2-MeTHF) is described. The phenol-TCT derivatives were readily prepared using grinding method in short time without further purification. This catalytic system allowed the facile C–O cleavage of phenol-TCT derivatives under mild reaction conditions with high efficiency and good functional group tolerance. Gram-scale reaction was also achieved. Particularly, sequential functionalization of phenol-TCT derivatives followed by C–O bond reduction could also be realized, affording the high value-added products in moderate to good yields.

Microwave assisted synthesis of triaryl cyanurates

Rapid synthesis of triaryl cyanurates(2,4,6-triaryloxy-1,3,5-triazine) was carried out by reacting cyanuric chloride with the sodium salt of hydroxyaryl compounds in water using focused microwaves. Environmentally friendly procedure and isolation of pure products in excellent yields are important features of this method.