19204-12-7

Basic information

• Product Name: 2-oxopropyl dimethylcarbamodithioate
• CAS NO: 19204-12-7
• Molecular Formula: C₆H₁₁NOS₂
• Molecular Weight: 177.2876
• Mol File: 19204-12-7.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 236.6°C at 760 mmHg
• Flash Point: 96.9°C
• Density: 1.174g/cm³
• Vapor Pressure: 0.0468mmHg at 25°C
• Refractive Index: 1.561
• CAS DataBase Reference: 2-oxopropyl dimethylcarbamodithioate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-oxopropyl dimethylcarbamodithioate(19204-12-7)
• EPA Substance Registry System: 2-oxopropyl dimethylcarbamodithioate(19204-12-7)

Safety Data

• Hazardous Substances Data: 19204-12-7(Hazardous Substances Data)

Upstream product

• 137-26-8 Thiram 
• 67-64-1 acetone 
• 598-64-1 dimethylammonium dimethyldithiocarbamate 
• 598-31-2 1-bromoacetone 
• 75-15-0 carbon disulfide 
• 124-40-3 dimethyl amine 
• 78-95-5 chloroacetone 
• 128-04-1 sodium dimethyldithiocarbamate 
• 90087-93-7 3-(dimethylthiocarbamoylthio)-2,4-pentanedione 
• 71-43-2 benzene 

Downstream Products

• 34683-69-7 dimethyl-dithiocarbamic acid-(2-hydroxyimino-propyl ester) 

Relevant articles and documents

TBD-catalyzed α-sulfenylation of cyclic ketones: Desymmetrization of 4-substituted cyclohexanones

A low loading of triazabicyclo[4.4.0]dec-5-ene (TBD) catalyzes the α-sulfenylation reaction of ketones employing tetramethylthiuram disulfide (TMTDS) as electrophilic reagent. This methodology is mild, effective and straightforward, rendering the desired products in high yield. Prochiral 4-substituted cyclohexanones can be desymmetrized with remarkable diastereoselectivity following this protocol. The dithiocarbamoyl function was shown to be easily removed upon reduction, affording thiols (1-mercaptan-2-ols).

Insecticidal hydrazone phosphates and phosphonates

Compounds having the formula STR1 in which R is lower alkyl or lower alkoxy, R1 is lower alkoxy, A is cycloalkyl, lower alkyl-substituted cycloalkenyl, or STR2 R2 and R3 are independently alkyl, aryl, aralkyl, cycloalkyl, hydrogen, or STR3 and R4 is lower alkyl. Compounds of this formula have been found to possess utility as insecticides, particularly against aphids and the housefly.