1927-59-9 Usage
General Description
2-Tert-butoxytetrahydrofuran is a chemical compound with the molecular formula C9H18O2. It is a colorless liquid with a mild, ether-like odor. 2-TERT-BUTOXYTETRAHYDROFURAN is commonly used as a solvent in chemical reactions and as a source of 2-tetrahydrofuranyl radicals in organic synthesis. It is also utilized as a protecting group for alcohols in organic chemistry. 2-Tert-butoxytetrahydrofuran is considered a moderately hazardous chemical, with potential health risks if inhaled, ingested, or comes into contact with skin. It is important to handle this substance with proper safety precautions, such as wearing protective gloves and eyewear.
Check Digit Verification of cas no
The CAS Registry Mumber 1927-59-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,9,2 and 7 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1927-59:
(6*1)+(5*9)+(4*2)+(3*7)+(2*5)+(1*9)=99
99 % 10 = 9
So 1927-59-9 is a valid CAS Registry Number.
InChI:InChI=1/C8H16O2/c1-8(2,3)10-7-5-4-6-9-7/h7H,4-6H2,1-3H3
1927-59-9Relevant articles and documents
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Sosnovsky
, p. 874 (1960)
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Amberlyst-15-catalyzed one-pot synthesis of 2-aryltetrahydrofurans from tetrahydrofuran
Gunduz, Hande,Kumbaraci, Volkan,Talinli, Naciye
supporting information, p. 2473 - 2476,4 (2012/12/13)
A simple one-step route for the conversion of naphthols and phenols with tetrahydrofuran into corresponding 2-aryltetrahydrofurans using Amberlyst-15 as a catalyst is reported. This is the first example of the acid-mediated formation and rearrangement reactions of tetrahydrofuranyl ethers prepared from the tetrahydrofuran and aromatic/aliphatic hydroxy compounds.
Decomposition Induite de Peroxydes Acetyleniques
Lemee, Laurent,Bourgeois, Marie-Josephe,Montaudon, Evelyne
, p. 467 - 472 (2007/10/03)
Acetylenic peroxides react as radicals in good hydrogen-donor solvents.Addition to the triple bond leads to monoadducts and attack on the O-O bond gives unsaturated acetals.The intermediate vinyl radical obtained in the first case does not seem to lead to homolytic intramolecular substitution.Unlike their ethylenic homologous these compounds are not unsaturated heterocycle precursors.
