19422-37-8Relevant articles and documents
An unprecedented oxidative intermolecular homo coupling reaction between two sp3C–sp3C centers under metal-free condition
Sahoo, Santosh K.
, p. 3476 - 3480 (2016)
An unprecedented formation of benzylic sp3C–sp3C coupled dibenzylic products has been illustrated. The reactions have been carried out in the presence of three oxidizing reagents, i.e., diacetoxy-iodobenzene (IBDA), N-fluorobenzenesulfonimide (NFSI), and pyridine (Py) using toluene derivatives.
Use of Isopropyl Alcohol as a Reductant for Catalytic Dehydoxylative Dimerization of Benzylic Alcohols Utilizing Ti?O Bond Photohomolysis
Iwasawa, Nobuharu,Sumiyama, Keiichi,Toriumi, Naoyuki
supporting information, p. 2474 - 2478 (2021/06/25)
Photohomolysis of Ti?O bonds is utilized in photocatalytic generation of titanium(III) species for dehydroxylative dimerization of benzylic alcohols under UV-light irradiation by using isopropyl alcohol (IPA) as a stoichiometric reductant. In this reaction, IPA works not as a single-electron donor as in the photo-redox catalyzed reactions but as an H-atom-donor. The reaction also proceeds under visible-light irradiation in the presence of thioglycolic acid as a ligand.
Oxidative generation of diarylcarbenium ion pools
Okajima, Masayuki,Soga, Kazuya,Nokami, Toshiki,Suga, Seiji,Yoshida, Jun-Ichi
, p. 5005 - 5007 (2007/10/03)
(Figure Presented) "Cation pools" of diarylcarbenium ions have been generated by the oxidative C-H bond dissociation of diarylmethanes using anodic oxidation. "Diarylcarbenium ion pools" thus generated react with various nucleophiles, such as allylsilanes