198022-17-2

Basic information

• Product Name: (3S,4R)-1-[bis(trimethylsilyl)methyl]-4-phenyl-3-[(4S,5R)-4,5-diphenyl-2-oxo-oxazolidin-3-yl]-azetidin-2-one
• Synonyms: (3S,4R)-1-[bis(trimethylsilyl)methyl]-4-phenyl-3-[(4S,5R)-4,5-diphenyl-2-oxo-oxazolidin-3-yl]-azetidin-2-one
• CAS NO: 198022-17-2
• Molecular Weight: 542.825
• Mol File: 198022-17-2.mol

Chemical Properties

• CAS DataBase Reference: (3S,4R)-1-[bis(trimethylsilyl)methyl]-4-phenyl-3-[(4S,5R)-4,5-diphenyl-2-oxo-oxazolidin-3-yl]-azetidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4R)-1-[bis(trimethylsilyl)methyl]-4-phenyl-3-[(4S,5R)-4,5-diphenyl-2-oxo-oxazolidin-3-yl]-azetidin-2-one(198022-17-2)
• EPA Substance Registry System: (3S,4R)-1-[bis(trimethylsilyl)methyl]-4-phenyl-3-[(4S,5R)-4,5-diphenyl-2-oxo-oxazolidin-3-yl]-azetidin-2-one(198022-17-2)

Safety Data

• Hazardous Substances Data: 198022-17-2(Hazardous Substances Data)

Upstream product

• 198021-38-4 [(4S,5R)-4,5-diphenyloxazolidin-2-on-3-yl]acetic acid 
• 100-52-7 benzaldehyde 
• 134340-00-4 bis(trimethylsilyl)methylamine 
• 23204-70-8 (4S,5R)-4,5-diphenyl-1,3-oxazolidin-2-one 
• 123016-86-4 Benzylideneamine 
• 198021-41-9 [(4S,5R)-2-oxo-4,5-diphenyloxazolidin-3-yl]acetyl chloride 

Relevant articles and documents

A contribution to the asymmetric synthesis of 3-amine β-lactams: The diastereoselective [2+2] cycloaddition reaction of chiral aminoketene equivalents with enolizable aldehyde-derived/mines

N-[Bis(trimethylsilyl)methyl]imines 9 show unique chemical properties when compared with conventional imines. Their reaction with optically pure aminoketenes derived from dehydrochlorination of 14 and 15 affords the corresponding 3-amino-4-alkyl-β-lactams