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19986-25-5

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19986-25-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 19986-25-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,9,9,8 and 6 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 19986-25:
(7*1)+(6*9)+(5*9)+(4*8)+(3*6)+(2*2)+(1*5)=165
165 % 10 = 5
So 19986-25-5 is a valid CAS Registry Number.

19986-25-5Relevant articles and documents

Mo(CO)6-INDUCED N-O BOND CLEAVAGE OF ISOXAZOLES. A CONVENIENT ROUTE TO PYRIDIN-4(1H)-ONES

Nitta, Makoto,Higuchi, Takanobu

, p. 853 - 858 (1994)

The Mo(CO)6-induced reaction of 3-methyl-5-(2-oxoalkyl)isoxazoles, which are derived through proton-abstraction of 3,5-dimethylisoxazole followed by treatment with esters, gave pyridin-4(1H)-ones in good to modest yields in a single step.

Heterocycle-bearing thio phenol compounds, intermediates for the preparation of the same and processes for the preparation of both

-

Page column 13, (2010/11/29)

Novel thio phenol compounds bearing heterocyclic groups as the substituent, useful as intermediates for the preparation of agricultural chemicals, particularly herbicides; intermediates for the preparation of the same; and processes for the preparation of both as represented by reaction formula (I), herein R1is C1-C4alkyl; R2is hydrogen or C1-C4alkyl; R3is hydrogen cyano, amido, C1-C4alkylcarbonyl or C1-C4alkoxycarbonyl; R4is C1-C4alkyl; and Q is isoxazolyl or the like.

Homochiral (R)- and (S)-1-heteroaryl- and 1-aryl-2-propanols via microbial redox

Fogagnolo, Marco,Giovannini, Pier Paolo,Guerrini, Alessandra,Medici, Alessandro,Pedrini, Paola,Colombi, Nicola

, p. 2317 - 2327 (2007/10/03)

Preparation of various heteroaryl propanols 2a-g and of the corresponding propanones 3a-g as starting materials for microbial redox is described. The kinetic resolution of the racemic propanols 2a-g is obtained via oxidation with Pseudomonas paucimobilis and Bacillus stearothermophilus [(R)-alcohols, ee 74-100%]. Similar results are achieved with 3-(2- hydroxypropyl)trifluoromethylbenzene 7 (44%, ee 100% of the (R)-alcohol 6). The reduction of the propanones 3a-d and 3g with baker's yeast and other fungi gives the (S)-alcohols (ee 100%). The pure (S)-alcohols are also obtained by reduction of 1-[3-(trifluoromethyl)phenyl]-2-propanone 7. 1- [(4,4-Dimethyl)-2-(Δ2)oxazolinyl]-2-propanone 3e and 1[2-(Δ2)- thiazolinyl)-2-propanone 3f are not reduced. The heterocyclic rings of (S)- 5-(2-hydroxypropyl)-3-methylisoxazole 2d and of (S)-2-(2-hydroxypropyl)-4- methylthiazole 2g are deblocked to the homochiral enamino ketone 8 (78%) and to the protected β-hydroxy aldehyde 9 (73%), respectively. The (R)-3-(2- hydroxypropyl)trifluoromethylbenzene 6 is transformed into the homochiral precursor of (S)-fenfluramine 10 (overall yield 65%).

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