207352-09-8

Basic information

• Product Name: 2-phenyl-3-methoxycarbonyl-4,5-diphenylfuran
• Synonyms: 2-phenyl-3-methoxycarbonyl-4,5-diphenylfuran
• CAS NO: 207352-09-8
• Molecular Weight: 354.405
• Mol File: 207352-09-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-phenyl-3-methoxycarbonyl-4,5-diphenylfuran(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenyl-3-methoxycarbonyl-4,5-diphenylfuran(207352-09-8)
• EPA Substance Registry System: 2-phenyl-3-methoxycarbonyl-4,5-diphenylfuran(207352-09-8)

Safety Data

• Hazardous Substances Data: 207352-09-8(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 100-52-7 benzaldehyde 
• 4440-01-1 lithium phenylacetylide 
• 186581-53-3 diazomethane 
• 872304-29-5 2,4,5-triphenyl-furan-3-carboxylic acid 
• 7338-94-5 1,3-diphenyl-2-propynone 
• 614-27-7 methyl 3-oxo-3-phenylpropionate 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 53751-25-0 3-bromo-2,4,5-triphenylfuran 

Relevant articles and documents

Nucleophilic Migratory Cyclopropenation of Activated Alkynes: A Nonmetal Approach to Unbiased Cyclopropenes

An unprecedented reductive [2 + 1] annulation of α-keto esters with alkynones mediated by P(NMe2)3 is described. Although this nonmetal cyclopropenation is a nucleophilic process, attributed to the ester migration via a formal [2 + 2] cycloaddition reaction of Kukhtin-Ramirez adducts and alkynones followed by a fragmentation, cyclopropenes with an unbiased alkene scaffold are formed in good to excellent yields, thus providing a promising complementarity to electrophilic metal-catalyzed cyclopropenation.

Direct synthesis of highly substituted furans from acyloins and active methylene compounds catalyzed by bismuth triflate

Bi(OTf)3 was found to be an effective catalyst for a tandem condensation/cyclization of acyloins and β-diketones or β-keto esters to afford highly substituted furans in good yields.