20912-69-0

Basic information

• Product Name: 1-chloro-4-(4-methoxyphenyl)sulfanyl-benzene
• Synonyms: 1-chloro-4-(4-methoxyphenyl)sulfanyl-benzene
• CAS NO: 20912-69-0
• Molecular Formula: C₁₃H₁₁ClOS
• Molecular Weight: 250.74
• Mol File: 20912-69-0.mol
• Article Data: 53

Chemical Properties

• Melting Point: 60-61 °C
• Boiling Point: 390.6°Cat760mmHg
• Flash Point: 190°C
• Appearance: /
• Density: 1.26g/cm³
• Vapor Pressure: 5.89E-06mmHg at 25°C
• Refractive Index: 1.633
• CAS DataBase Reference: 1-chloro-4-(4-methoxyphenyl)sulfanyl-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-4-(4-methoxyphenyl)sulfanyl-benzene(20912-69-0)
• EPA Substance Registry System: 1-chloro-4-(4-methoxyphenyl)sulfanyl-benzene(20912-69-0)

Safety Data

• Hazardous Substances Data: 20912-69-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H11ClOS/c1-15-11-4-8-13(9-5-11)16-12-6-2-10(14)3-7-12/h2-9H,1H3

Upstream product

• 106-54-7 p-Chlorothiophenol 
• 1679-18-1 4-Chlorophenylboronic acid 
• 98-68-0 4-methoxy-phenyl-sulphonyl chloride 
• 673-41-6 p-chlorobenzenediazonium tetrafluoroborate 
• 16913-61-4 dimethyl-dithiocarbamic acid 4-chloro-phenyl ester 
• 104-94-9 4-methoxy-aniline 
• 696-63-9 4-Methoxybenzenethiol 
• 1073-69-4 N-4-chlorophenylhydrazine 
• 5720-07-0 4-methoxyphenylboronic acid 
• 1073-70-7 4-chlorophenylhydrazine hydrochloride 
• 21130-91-6 triethoxy(4-methoxyphenyl)silane 
• 30384-54-4 sodium S-(4-chlorophenyl) thiosulfate 
• 1950-68-1 4-methoxybenzenesulfonyl hydrazide 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 

Downstream Products

• 60893-38-1 1-chloro-4-((4-methoxyphenyl)sulfonyl)benzene 
• 75736-88-8 1-chloro-4-((4-methoxyphenyl)sulfinyl)benzene 

Relevant articles and documents

A water soluble Ni-Schiff base complex for homogeneous green catalytic C[sbnd]S cross-coupling reactions

Since the embarkation of C[sbnd]S cross-coupling from aryl halides with thiols a handful of works have been contemplated in aqueous medium. Herein, we report an example of a water soluble Ni-Schiff base complex as the green catalyst for the synthesis of t

Ni-catalyzed C–S bond cleavage of aryl 2-pyridyl thioethers coupling with alkyl and aryl thiols

A nickel-catalyzed C–SPy bond activation reactions to produce a variety of thioethers has been developed. The reaction is promoted by a user-friendly, inexpensive, air and moisture-stable Ni precatalyst. Various aryl 2-pyridyl thioethers and a wide range of alkyl and aryl thiols substrates were tolerated in this process which afforded products in moderate to excellent yields.

Forging C?S(Se) Bonds by Nickel-catalyzed Decarbonylation of Carboxylic Acid and Cleavage of Aryl Dichalcogenides

A nickel-catalyzed decarbonylation of carboxylic acids cross-coupling protocol has been developed for the straightforward C?S(Se) bond formation. This reaction is promoted by a commercially-available, user-friendly, inexpensive, air and moisture-stable nickel precatalyst. Various carboxylic acids and a wide range of aryl dichalcogenide substrates were tolerated in this process which afforded products in good to excellent yields. In addition, the present reaction can be conducted on gram scale in good yield.