21062-16-8

Upstream product

• 78-75-1 1,2-Dibromopropane 
• 108-98-5 thiophenol 
• 7594-43-6 isopropenyl phenyl sulfide 
• 421-50-1 1,1,1-trifluoro-2-propanone 
• 5296-64-0 allyl phenyl thioether 
• 26307-20-0 2,2'-bis(phenylthio)-2,2'-azopropane 
• 32300-42-8 1-Phenylthio-2-mesyloxypropan 
• 4873-09-0 allyl tosylate 
• 107-05-1 3-chloroprop-1-ene 
• 556-56-9 allyl iodid 
• 106-95-6 allyl bromide 
• 882-33-7 diphenyldisulfane 
• 75-56-9 methyloxirane 

Downstream Products

• 38377-19-4 1,2-bis-benzenesulfonyl-propane 

Relevant academic research and scientific papers

Silica: An efficient catalyst for one-pot regioselective synthesis of dithioethers

The development of a silica-promoted highly selective synthesis of 1,2 or 1,3-dithioethers via solvent-free one-pot tandem reactions of an allyl bromide with excess thiol at room temperature is described. The choice of silica gel, either pre-calcined or moistened with water, exhibited notable regioselectivity in the formation of dithioethers. Plausible mechanistic routes were explored and postulated.

Studies on Organic Fluorine Compounds. IL. The Ene Reaction of Trifluoroacetone

The ene reaction of 1,1,1-trifluoroacetone with various olefinic compounds proceeded in the presence of aluminum chloride at low temperature to give allylmethyl (trifluoromethyl)carbinols.Olefinic compounds with a terminal vinyl group reacted smoothly, but some olefins with an inner double bond did not react at all.Trifluoroacetone was also found to undergo a Friedel-Crafts type reaction with aromatic compounds.Keywords - trifluoroacetone; trifluoromethyl; ene reaction; homoallyl alcohol; trifluoromethylcarbinol; Lewis acid catalyzed reaction; aluminum chloride; allyl; olefin; diethyl aluminum chloride