2123-92-4

Basic information

• Product Name: tert-butyl peroxycinnamate
• Synonyms: tert-butyl peroxycinnamate;3-Phenyl-2-propeneperoxoic acid tert-butyl ester;Einecs 218-338-4
• CAS NO: 2123-92-4
• Molecular Formula: C₁₃H₁₆O₃
• Molecular Weight: 220.26434
• EINECS: 218-338-4
• Mol File: 2123-92-4.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 291.1°C at 760 mmHg
• Flash Point: 102.4°C
• Appearance: /
• Density: 1.067g/cm³
• Vapor Pressure: 0.00199mmHg at 25°C
• Refractive Index: 1.534
• CAS DataBase Reference: tert-butyl peroxycinnamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl peroxycinnamate(2123-92-4)
• EPA Substance Registry System: tert-butyl peroxycinnamate(2123-92-4)

Safety Data

• Hazardous Substances Data: 2123-92-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H16O3/c1-13(2,3)16-15-12(14)10-9-11-7-5-4-6-8-11/h4-10H,1-3H3/b10-9+

Upstream product

• 75-91-2 tert.-butylhydroperoxide 
• 102-92-1 Cinnamoyl chloride 
• 71721-74-9 trans-Zimtsaeure-p-nitrophenylester 
• 109299-93-6 3-((E)-3-phenyl-2-propenoyl)-1,3-oxazolidin-2-one 
• 656821-45-3 3-phenyl acrylic acid pentafluorophenyl ester 
• 370084-24-5 (E)-3-Phenyl-1-[1,2,4]triazol-1-yl-propenone 
• 1138-15-4 cinnamoyl imidazole 
• 67-56-1 methanol 
• 110-05-4 di-tert-butyl peroxide 
• 104-55-2 3-phenyl-propenal 

Downstream Products

• 27046-68-0 3,5-diphenyl-4,5-dihydro-isoxazole-4-carboperoxoic acid tert-butyl ester 
• 48170-02-1 triethyltin cinnamate 
• 17421-58-8 (C₂H₅)3SnCHCHC₆H₅ 
• 17431-39-9 (E)-N,N-dimethylcinnamamide 

Relevant articles and documents

Sunlight assisted solvent free synthesis of tert-butylperesters

A green and efficient methodology has been developed for the direct conversion of aryl aldehydes to the corresponding tert-butyl peresters. The reaction has been carried out in absence of any solvent and the sunlight is used as the green source of energy. In this reaction tetrabutylammonium iodide (TBAI) acts as the mild organo catalyst and tert-butyl hydroperoxide (TBHP) serve as the source of tert-butyl group.

Catalytic asymmetric synthesis of α,β-epoxy esters, aldehydes, amides, and γ,δ-epoxy β-keto esters: Unique reactivity of α,β-unsaturated carboxylic acid imidazolides [16]

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